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@ARTICLE{Uddin:1006570,
author = {Uddin, Nasir and Sun, Zhehao and Langley, Julien and Lu,
Haijao and Cao, Pengfei and Wibowo, Ary and Yin, Xinmao and
Tang, Chi Sin and Nguyen, Hieu T. and Evans, Jack D. and Li,
Xinzhe and Zhang, Xiaoliang and Heggen, Marc and
Dunin-Borkowski, Rafal E. and Wee, Andrew T. S. and Zhao,
Haitao and Cox, Nicholas and Yin, Zongyou},
title = {{U}ltrabroadband plasmon driving selective photoreforming
of methanol under ambient conditions},
journal = {Proceedings of the National Academy of Sciences of the
United States of America},
volume = {120},
number = {3},
issn = {0027-8424},
address = {Washington, DC},
publisher = {National Acad. of Sciences},
reportid = {FZJ-2023-01718},
pages = {e2212075120},
year = {2023},
abstract = {Photoreforming of methanol has been envisioned as a
promising pathway to produce H2 fuel which gained interest
over the years. However, the formation of CO2/CO byproducts
from this pathway has seen as a major hurdle to its
practical realization because the evolution of CO2 and/or CO
gases will negatively contribute toward the global-warming
and/or environmental issues. To resolve these issues,
herein, we discovered solar-driven ultrabroadband plasmonic
photoreforming of pure methanol to pure, green and
self-separable H2 energy production with zero-emission from
an all-plasmonic Cu–WC/W catalytic system. The local
electric field, lattice misfit strain, and the
monodirectional flow of charge carriers by optical
dielectric gradient work in synergy to enable the superior
plasmonic photocatalysis in this all-plasmonic system.},
cin = {ER-C-1},
ddc = {500},
cid = {I:(DE-Juel1)ER-C-1-20170209},
pnm = {5351 - Platform for Correlative, In Situ and Operando
Characterization (POF4-535) / 5353 - Understanding the
Structural and Functional Behavior of Solid State Systems
(POF4-535)},
pid = {G:(DE-HGF)POF4-5351 / G:(DE-HGF)POF4-5353},
typ = {PUB:(DE-HGF)16},
pubmed = {36634137},
UT = {WOS:001179845800001},
doi = {10.1073/pnas.2212075120},
url = {https://juser.fz-juelich.de/record/1006570},
}