TY - JOUR
AU - Anop, Hanna
AU - Buitenhuis, Johan
TI - Polyelectrolyte Complexes from Oppositely Charged Filamentous Viruses
JO - Langmuir
VL - 39
IS - 13
SN - 0743-7463
CY - Washington, DC
PB - ACS Publ.
M1 - FZJ-2023-01763
SP - 4545 - 4556
PY - 2023
AB - Here, we present an explorative study on a new type of polyelectrolyte complex made from chemically modified filamentous fd viruses. The fd virus is a semiflexible rod-shaped bacteriophage with a length of 880 nm and a diameter of 6.6 nm, which has been widely used as a well-defined model system of colloidal rods to investigate phase, flow, and other behavior. Here, chemically modified viruses have been prepared to obtain two types with opposite electrical charges in addition to a steric stabilization layer by poly(ethylene glycol) (PEG) grafting. The complex formation of stoichiometric mixtures of these oppositely charged viruses is studied as a function of virus and salt concentration. Furthermore, static light scattering measurements show a varying, strong increase in scattering intensity in some samples without visual macroscopic complex formation. Finally, the results of the complex formation are rationalized by comparing to model calculations on the pair interaction potential between oppositely charged viruses.
LB - PUB:(DE-HGF)16
C6 - 36947868
UR - <Go to ISI:>//WOS:000952045500001
DO - DOI:10.1021/acs.langmuir.2c02790
UR - https://juser.fz-juelich.de/record/1006630
ER -