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@INPROCEEDINGS{Dhont:1007832,
author = {Dhont, Jan K.G.},
title = {{S}ingle-{P}article {T}hermophoresis and {E}lectric-{F}ield
{I}nduced {P}hases/{S}tates},
school = {Universidad Veracruzana},
reportid = {FZJ-2023-02217},
year = {2023},
abstract = {In the first part of this presentation, I will discuss
colloidal mass transport induced by temperature gradients
(commonly referred to as thermophoresis) resulting from the
electric double layer of charged spherical colloids. There
are three contributions to the thermophoresis of charged
colloids. The temperature dependence of the internal energy
of the electric double layer leads to migration from high to
low temperatures. The temperature-gradient induced asymmetry
of the double layer gives rise to an electrostatic force
onto the surface charges of the colloid. Finally, the
asymmetry of the double layer leads to an electro osmotic
flow, that acts with a friction force onto the core of the
colloid. All three contributions will be discussed, and the
theoretical results will be compared to experiments. In the
second part, the phases and dynamical states that are
induced by external electric fields in a system of very long
and thin and highly charged rod-like colloids will be
discussed. The experimental phase/state diagram, for a
concentration within the two-phase isotropic-nematic
coexistence region, will be presented. Depending on the
electric field strength and the frequency, several
phase/state-transitions are induced: a transition from
nematic to chiral nematic, from a nematic to a homeotropic
state, and a transition to a dynamical state where nematic
domains persistently melt and reform. An explanation of
these phenomena is presented, both on an intuitive level and
based on the Smoluchowski equation, which is an equation of
motion for the probability density function for the
positions and orientations of the rods.},
month = {Mar},
date = {2023-03-21},
organization = {Dispersions of charged particles: A
century of theoretical development,
Xalapa (Mexico), 21 Mar 2023 - 22 Mar
2023},
subtyp = {Invited},
cin = {IBI-4},
cid = {I:(DE-Juel1)IBI-4-20200312},
pnm = {5243 - Information Processing in Distributed Systems
(POF4-524)},
pid = {G:(DE-HGF)POF4-5243},
typ = {PUB:(DE-HGF)6},
url = {https://juser.fz-juelich.de/record/1007832},
}