001008187 001__ 1008187
001008187 005__ 20240711085649.0
001008187 020__ $$a978-3-95806-694-6
001008187 0247_ $$2datacite_doi$$a10.34734/FZJ-2023-02233
001008187 037__ $$aFZJ-2023-02233
001008187 1001_ $$0P:(DE-Juel1)176118$$aYe, Ruijie$$b0$$eCorresponding author$$ufzj
001008187 245__ $$aSustainable Fabrication of Ceramic Solid Electrolytes for Solid-State Lithium Batteries$$f - 2023-07-17
001008187 260__ $$aJülich$$bForschungszentrum Jülich GmbH Zentralbibliothek, Verlag$$c2023
001008187 300__ $$avi, 119
001008187 3367_ $$2DataCite$$aOutput Types/Dissertation
001008187 3367_ $$0PUB:(DE-HGF)3$$2PUB:(DE-HGF)$$aBook$$mbook
001008187 3367_ $$2ORCID$$aDISSERTATION
001008187 3367_ $$2BibTeX$$aPHDTHESIS
001008187 3367_ $$02$$2EndNote$$aThesis
001008187 3367_ $$0PUB:(DE-HGF)11$$2PUB:(DE-HGF)$$aDissertation / PhD Thesis$$bphd$$mphd$$s1689595259_31383
001008187 3367_ $$2DRIVER$$adoctoralThesis
001008187 4900_ $$aSchriften des Forschungszentrums Jülich Reihe Energie & Umwelt / Energy & Environment$$v607
001008187 502__ $$aDissertation, RWTH Aachen University, 2023$$bDissertation$$cRWTH Aachen University$$d2023
001008187 520__ $$aSolid-state lithium batteries (SSLBs) are considered to be one of the most promising nextgeneration Li batteries due to their high capacity and intrinsic safety. Their sustainable processing offers additional advantages over conventional batteries in terms of ecological and economicbenefits. However, the sustainable processing of SSLBs has been only sporadically investigated and need to be optimized. Garnet-type Li7La3Zr2O12 (LLZO) is one representative of oxide-based solid electrolytes (SE) for SSLBs. A thin freestanding LLZO sheet can be fabricated by tape-casting and used e.g. as separator in SSLBs, since tape-casting is an industrially established process and enables large-scale production of such SEs. However, organic solvents and additives employed in conventional slurry recipes for tape-casting give rise to health and safety concerns and additionally cause high cost for solvent recovery. Hence, development of a water-based processing route reduces both manufacturing costs and environmental footprint. In this work, a tape-casting process for LLZO SEs is developed using water as solvent, the watersolublebiopolymer as binder and other harmless polymers as plasticizers. During the aqueous  processing, a Li+/H+ exchange takes place, but this Li+/H+ exchange reaction is reversible in the procedure and results in the formation of stoichiometric cubic LLZO at the end. The obtained freestanding LLZO thin sheets have a relative density of 90% to the theoretical density and exhibit an ionic conductivity of 0.15 mS cm-1 at room temperature.
001008187 536__ $$0G:(DE-HGF)POF4-899$$a899 - ohne Topic (POF4-899)$$cPOF4-899$$fPOF IV$$x0
001008187 8564_ $$uhttps://juser.fz-juelich.de/record/1008187/files/Energie_Umwelt_607.pdf$$yOpenAccess
001008187 909CO $$ooai:juser.fz-juelich.de:1008187$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
001008187 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)176118$$aForschungszentrum Jülich$$b0$$kFZJ
001008187 9131_ $$0G:(DE-HGF)POF4-899$$1G:(DE-HGF)POF4-890$$2G:(DE-HGF)POF4-800$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bProgrammungebundene Forschung$$lohne Programm$$vohne Topic$$x0
001008187 9141_ $$y2023
001008187 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
001008187 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
001008187 920__ $$lyes
001008187 9201_ $$0I:(DE-Juel1)IEK-1-20101013$$kIEK-1$$lWerkstoffsynthese und Herstellungsverfahren$$x0
001008187 9801_ $$aFullTexts
001008187 980__ $$aphd
001008187 980__ $$aVDB
001008187 980__ $$aUNRESTRICTED
001008187 980__ $$abook
001008187 980__ $$aI:(DE-Juel1)IEK-1-20101013
001008187 981__ $$aI:(DE-Juel1)IMD-2-20101013