Hauptseite > Publikationsdatenbank > Sustainable Fabrication of Ceramic Solid Electrolytes for Solid-State Lithium Batteries > print

001     1008187
005     20240711085649.0
020 _ _ |a 978-3-95806-694-6
024 7 _ |a 10.34734/FZJ-2023-02233
|2 datacite_doi
037 _ _ |a FZJ-2023-02233
100 1 _ |a Ye, Ruijie
|0 P:(DE-Juel1)176118
|b 0
|e Corresponding author
|u fzj
245 _ _ |a Sustainable Fabrication of Ceramic Solid Electrolytes for Solid-State Lithium Batteries
|f - 2023-07-17
260 _ _ |a Jülich
|c 2023
|b Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag
300 _ _ |a vi, 119
336 7 _ |a Output Types/Dissertation
|2 DataCite
336 7 _ |a Book
|0 PUB:(DE-HGF)3
|2 PUB:(DE-HGF)
|m book
336 7 _ |a DISSERTATION
|2 ORCID
336 7 _ |a PHDTHESIS
|2 BibTeX
336 7 _ |a Thesis
|0 2
|2 EndNote
336 7 _ |a Dissertation / PhD Thesis
|b phd
|m phd
|0 PUB:(DE-HGF)11
|s 1689595259_31383
|2 PUB:(DE-HGF)
336 7 _ |a doctoralThesis
|2 DRIVER
490 0 _ |a Schriften des Forschungszentrums Jülich Reihe Energie & Umwelt / Energy & Environment
|v 607
502 _ _ |a Dissertation, RWTH Aachen University, 2023
|c RWTH Aachen University
|b Dissertation
|d 2023
520 _ _ |a Solid-state lithium batteries (SSLBs) are considered to be one of the most promising nextgeneration Li batteries due to their high capacity and intrinsic safety. Their sustainable processing offers additional advantages over conventional batteries in terms of ecological and economicbenefits. However, the sustainable processing of SSLBs has been only sporadically investigated and need to be optimized. Garnet-type Li7La3Zr2O12 (LLZO) is one representative of oxide-based solid electrolytes (SE) for SSLBs. A thin freestanding LLZO sheet can be fabricated by tape-casting and used e.g. as separator in SSLBs, since tape-casting is an industrially established process and enables large-scale production of such SEs. However, organic solvents and additives employed in conventional slurry recipes for tape-casting give rise to health and safety concerns and additionally cause high cost for solvent recovery. Hence, development of a water-based processing route reduces both manufacturing costs and environmental footprint. In this work, a tape-casting process for LLZO SEs is developed using water as solvent, the watersolublebiopolymer as binder and other harmless polymers as plasticizers. During the aqueous processing, a Li+/H+ exchange takes place, but this Li+/H+ exchange reaction is reversible in the procedure and results in the formation of stoichiometric cubic LLZO at the end. The obtained freestanding LLZO thin sheets have a relative density of 90% to the theoretical density and exhibit an ionic conductivity of 0.15 mS cm-1 at room temperature.
536 _ _ |a 899 - ohne Topic (POF4-899)
|0 G:(DE-HGF)POF4-899
|c POF4-899
|f POF IV
|x 0
856 4 _ |u https://juser.fz-juelich.de/record/1008187/files/Energie_Umwelt_607.pdf
|y OpenAccess
909 C O |o oai:juser.fz-juelich.de:1008187
|p openaire
|p open_access
|p VDB
|p driver
|p dnbdelivery
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 0
|6 P:(DE-Juel1)176118
913 1 _ |a DE-HGF
|b Programmungebundene Forschung
|l ohne Programm
|1 G:(DE-HGF)POF4-890
|0 G:(DE-HGF)POF4-899
|3 G:(DE-HGF)POF4
|2 G:(DE-HGF)POF4-800
|4 G:(DE-HGF)POF
|v ohne Topic
|x 0
914 1 _ |y 2023
915 _ _ |a OpenAccess
|0 StatID:(DE-HGF)0510
|2 StatID
915 _ _ |a Creative Commons Attribution CC BY 4.0
|0 LIC:(DE-HGF)CCBY4
|2 HGFVOC
920 _ _ |l yes
920 1 _ |0 I:(DE-Juel1)IEK-1-20101013
|k IEK-1
|l Werkstoffsynthese und Herstellungsverfahren
|x 0
980 1 _ |a FullTexts
980 _ _ |a phd
980 _ _ |a VDB
980 _ _ |a UNRESTRICTED
980 _ _ |a book
980 _ _ |a I:(DE-Juel1)IEK-1-20101013
981 _ _ |a I:(DE-Juel1)IMD-2-20101013

LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21