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@ARTICLE{Shchur:1008996,
      author       = {Shchur, Yaroslav and Bendak, Andrii and Beltramo, Guillermo
                      and Andrushchak, Anatoliy S. and Vitusevich, Svetlana and
                      Pustovyj, Denys and Sahraoui, Bouchta and Slyvka, Yurii and
                      Kityk, Andriy V.},
      title        = {{N}anoarhitectonics of {I}norganic–{O}rganic
                      {S}ilica–{B}enzil {C}omposites: {S}ynthesis, {N}anocrystal
                      {M}orphology and {M}icro-{R}aman {A}nalysis},
      journal      = {Nanomaterials},
      volume       = {13},
      number       = {13},
      issn         = {2079-4991},
      address      = {Basel},
      publisher    = {MDPI},
      reportid     = {FZJ-2023-02567},
      pages        = {1913 -},
      year         = {2023},
      abstract     = {The synthesis of nanosized organic benzil (C6H5CO)2
                      crystals within the mesoporous SiO2 host matrix was
                      investigated via X-ray diffraction, transmission electron
                      microscopy, Raman spectroscopy, and ab initio lattice
                      dynamics analysis. Combining these methods, we have proved
                      that the main structural properties of benzil nanocrystals
                      embedded into SiO2 host membranes with pore diameters of
                      6.0, 7.8, 9.4, and 13.0 nm are preserved compared to a bulk
                      benzil crystal. Space confinement has an insignificant
                      impact on the lattice vibrational properties of benzil
                      crystals implanted into the host matrices. The ab initio
                      lattice dynamics calculation of the phonon spectrum in the
                      Brillouin zone center shows the mechanical and dynamical
                      stability of benzil lattice, revealing very low optical
                      frequency of 11 cm−1 at point Γ.},
      cin          = {IBI-2},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IBI-2-20200312},
      pnm          = {5243 - Information Processing in Distributed Systems
                      (POF4-524)},
      pid          = {G:(DE-HGF)POF4-5243},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {37446429},
      UT           = {WOS:001032285100001},
      doi          = {10.3390/nano13131913},
      url          = {https://juser.fz-juelich.de/record/1008996},
}