% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Zarzana:1009000,
      author       = {Zarzana, Christopher A. and McAlpine, Jack and Wilden,
                      Andreas and Hupert, Michelle and Stärk, Andrea and Iqbal,
                      Mudassir and Verboom, Willem and Mincher, Bruce J. and
                      Groenewold, Gary S. and Modolo, Giuseppe},
      title        = {{G}amma {R}adiolysis of {P}henyl-{S}ubstituted {TODGA}s:
                      {P}art {I}},
      journal      = {Solvent extraction and ion exchange},
      volume       = {41},
      number       = {5},
      issn         = {0736-6299},
      address      = {Philadelphia, PA},
      publisher    = {Taylor $\&$ Francis},
      reportid     = {FZJ-2023-02569},
      pages        = {564-581},
      year         = {2023},
      abstract     = {The radiolytic stabilities of three phenylated analogs of
                      N,N,N',N'-tetraoctyl diglycolamide (TODGA) were
                      investigated:
                      2-(2-(di-n-octylamino)-2-oxoethoxy)-N,N-di-n-octyl-2-phenylacetamide
                      (PhTODGA), which has a phenyl substituent bound to a central
                      methylene,
                      2-(2-(di-n-octylamino)-2-oxo-1-phenylethoxy)-N,N-di-n-octylpropanamide
                      (PhMeTODGA), which also contains a methyl substituent bound
                      to the methylene on the other side of the ether moiety, and,
                      2-(2-N-n-hexyl-N-phenylamino)-2-oxoethoxy)-N-n-hexyl-N-phenylacetamide
                      (DHDPDGA), which has phenyl substituents located on the
                      amide groups instead of the central methylenes. The
                      objective of Part I of this series of papers covers was to
                      evaluate the contribution of the phenyl group to the
                      radiolytic stability of these diglycolamides when irradiated
                      in a) n-dodecane, and b) n-dodecane in the presence of a
                      nitric acid-containing aqueous phase. The results indicate
                      that the presence of the phenyl group decreases the overall
                      radiolytic stability compared to unsubstituted TODGA.
                      However, the results also indicate that the phenyl groups
                      interact with nitric acid in a cooperative fashion that
                      enhances the radiation stability of the phenylated
                      diglycolamide (DGA) derivatives in the presence of a nitric
                      acid-containing aqueous phase compared to irradiation in
                      only n-dodecane. The results are consistent with the
                      hypothesized formation of nitric acid-phenylated DGA
                      complexes in the n-dodecane phase that are significantly
                      more stable with respect to gamma irradiation, compared to
                      the phenylated DGA molecules alone.},
      cin          = {IEK-6 / ZEA-3},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-6-20101013 / I:(DE-Juel1)ZEA-3-20090406},
      pnm          = {1412 - Predisposal (POF4-141) / SACSESS - Safety of
                      ACtinide Separation proceSSes (323282) / GENIORS - GEN IV
                      Integrated Oxide fuels recycling strategies (755171)},
      pid          = {G:(DE-HGF)POF4-1412 / G:(EU-Grant)323282 /
                      G:(EU-Grant)755171},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:001023482500001},
      doi          = {10.1080/07366299.2023.2220765},
      url          = {https://juser.fz-juelich.de/record/1009000},
}