001009001 001__ 1009001
001009001 005__ 20240712084614.0
001009001 0247_ $$2doi$$a10.1080/07366299.2023.2221290
001009001 0247_ $$2ISSN$$a0736-6299
001009001 0247_ $$2ISSN$$a1532-2262
001009001 0247_ $$2datacite_doi$$a10.34734/FZJ-2023-02570
001009001 0247_ $$2WOS$$aWOS:001023475100001
001009001 037__ $$aFZJ-2023-02570
001009001 041__ $$aEnglish
001009001 082__ $$a540
001009001 1001_ $$00000-0001-9617-7123$$aZarzana, Christopher A.$$b0$$eCorresponding author
001009001 245__ $$aGamma Radiolysis of Phenyl-Substituted TODGAs: Part II
001009001 260__ $$aPhiladelphia, PA$$bTaylor & Francis$$c2023
001009001 3367_ $$2DRIVER$$aarticle
001009001 3367_ $$2DataCite$$aOutput Types/Journal article
001009001 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1692364975_8448
001009001 3367_ $$2BibTeX$$aARTICLE
001009001 3367_ $$2ORCID$$aJOURNAL_ARTICLE
001009001 3367_ $$00$$2EndNote$$aJournal Article
001009001 520__ $$aThe radiolytic degradation chemistry of three phenylated analogs of N,N,N’,N’-tetraoctyl diglycolamide (TODGA) was investigated: 2-(2-(di-n-octylamino)-2-oxoethoxy)-N,N-di-n-octyl-2-phenylacetamide (PhTODGA), which has a phenyl substituent bound to a central methylene, 2-(2-(di-n-octylamino)-2-oxo-1-phenylethoxy)-N,N-di-n-octylpropanamide (PhMeTODGA), which also contains a methyl substituent bound to the methylene on the other side of the ether moiety, and, 2-(2-N-n-hexyl-N-phenylamino)-2-oxoethoxy)-N-n-hexyl-N-phenylacetamide (DHDPDGA), which has phenyl substituents located on the amide groups instead of the central methylenes. In Part II of this series of papers radiolytic degradation products were identified after separation with liquid chromatography by High Resolution, Accurate-Mass mass spectrometry and collision-induced dissociation. At least twenty-two radiolytic degradation products were identified for PhTODGA, twenty-nine for PhMeTODGA, and over three dozen for DHDPDGA. The suite of radiolytic degradation products of these three investigated ligands was significantly larger than has been reported for previously studied diglycolamides, owing to their asymmetric nature, and to the identification of several new degradation mechanisms, including addition of methyl, hydroxyl, and nitrogen oxide radicals, that have not been previously reported for diglycolamides. Degradation products that contained addition of a NO2 or NO3 group were particularly prevalent for DHDPDGA, likely due to the phenyl side-groups. Several of these newly observed mechanisms do not appear to depend on the presence of the phenyl groups, suggesting these novel mechanisms may apply to other diglycolamides
001009001 536__ $$0G:(DE-HGF)POF4-1412$$a1412 - Predisposal (POF4-141)$$cPOF4-141$$fPOF IV$$x0
001009001 536__ $$0G:(EU-Grant)323282$$aSACSESS - Safety of ACtinide Separation proceSSes (323282)$$c323282$$fFP7-Fission-2012$$x1
001009001 536__ $$0G:(EU-Grant)755171$$aGENIORS - GEN IV Integrated Oxide fuels recycling strategies (755171)$$c755171$$fNFRP-2016-2017-1$$x2
001009001 588__ $$aDataset connected to CrossRef, Journals: juser.fz-juelich.de
001009001 7001_ $$0P:(DE-HGF)0$$aMcAlpine, Jack$$b1
001009001 7001_ $$0P:(DE-Juel1)130438$$aWilden, Andreas$$b2
001009001 7001_ $$0P:(DE-Juel1)142389$$aHupert, Michelle$$b3
001009001 7001_ $$0P:(DE-Juel1)133855$$aStärk, Andrea$$b4$$ufzj
001009001 7001_ $$00000-0002-9830-8235$$aIqbal, Mudassir$$b5
001009001 7001_ $$00000-0002-6863-8655$$aVerboom, Willem$$b6
001009001 7001_ $$0P:(DE-HGF)0$$aVandevender, Aspen N.$$b7
001009001 7001_ $$00000-0003-3108-2590$$aMincher, Bruce J.$$b8
001009001 7001_ $$00000-0001-9027-0490$$aGroenewold, Gary S.$$b9
001009001 7001_ $$0P:(DE-Juel1)130383$$aModolo, Giuseppe$$b10
001009001 773__ $$0PERI:(DE-600)2043256-2$$a10.1080/07366299.2023.2221290$$gp. 1 - 24$$n5$$p582-605 $$tSolvent extraction and ion exchange$$v41$$x0736-6299$$y2023
001009001 8564_ $$uhttps://juser.fz-juelich.de/record/1009001/files/Authors%20fulltext.pdf$$yPublished on 2023-07-06. Available in OpenAccess from 2024-07-06.$$zStatID:(DE-HGF)0510
001009001 8564_ $$uhttps://juser.fz-juelich.de/record/1009001/files/Restricted%20Fulltext.pdf$$yRestricted
001009001 8564_ $$uhttps://juser.fz-juelich.de/record/1009001/files/Supporting%20Information.pdf$$yRestricted
001009001 909CO $$ooai:juser.fz-juelich.de:1009001$$pdnbdelivery$$pec_fundedresources$$pVDB$$pdriver$$popen_access$$popenaire
001009001 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)130438$$aForschungszentrum Jülich$$b2$$kFZJ
001009001 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)142389$$aForschungszentrum Jülich$$b3$$kFZJ
001009001 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)133855$$aForschungszentrum Jülich$$b4$$kFZJ
001009001 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)130383$$aForschungszentrum Jülich$$b10$$kFZJ
001009001 9131_ $$0G:(DE-HGF)POF4-141$$1G:(DE-HGF)POF4-140$$2G:(DE-HGF)POF4-100$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF4-1412$$aDE-HGF$$bForschungsbereich Energie$$lNukleare Entsorgung, Sicherheit und Strahlenforschung (NUSAFE II)$$vNukleare Entsorgung$$x0
001009001 9141_ $$y2023
001009001 915__ $$0StatID:(DE-HGF)0530$$2StatID$$aEmbargoed OpenAccess
001009001 915__ $$0LIC:(DE-HGF)CCBYNC4$$2HGFVOC$$aCreative Commons Attribution-NonCommercial CC BY-NC 4.0
001009001 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2022-11-29
001009001 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2022-11-29
001009001 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz$$d2023-10-24$$wger
001009001 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bSOLVENT EXTR ION EXC : 2022$$d2023-10-24
001009001 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2023-10-24
001009001 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search$$d2023-10-24
001009001 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC$$d2023-10-24
001009001 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2023-10-24
001009001 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2023-10-24
001009001 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2023-10-24
001009001 915__ $$0StatID:(DE-HGF)9900$$2StatID$$aIF < 5$$d2023-10-24
001009001 920__ $$lyes
001009001 9201_ $$0I:(DE-Juel1)IEK-6-20101013$$kIEK-6$$lNukleare Entsorgung$$x0
001009001 9201_ $$0I:(DE-Juel1)ZEA-3-20090406$$kZEA-3$$lAnalytik$$x1
001009001 9801_ $$aFullTexts
001009001 980__ $$ajournal
001009001 980__ $$aVDB
001009001 980__ $$aUNRESTRICTED
001009001 980__ $$aI:(DE-Juel1)IEK-6-20101013
001009001 980__ $$aI:(DE-Juel1)ZEA-3-20090406
001009001 981__ $$aI:(DE-Juel1)IFN-2-20101013