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@ARTICLE{Zhao:1009697,
author = {Zhao, Tong and Kraft, Marvin and Zeier, Wolfgang},
title = {{S}ynthesis-{C}ontrolled {P}olymorphism and {A}nion
{S}olubility in the {S}odium-{I}on {C}onductor
${N}a_{3}{I}n{C}l_{6–x}{B}r_x$ (0 ≤ $x$ ≤ 2)},
journal = {Inorganic chemistry},
volume = {62},
number = {30},
issn = {0020-1669},
address = {Washington, DC},
publisher = {American Chemical Society},
reportid = {FZJ-2023-02942},
pages = {11737 - 11745},
year = {2023},
abstract = {Motivated by the significant transport property improvement
of the anion-substituted lithium metal halides, a series of
anion mixed solid solutions of Na3InCl6–xBrx (0 ≤ x ≤
2) are successfully synthesized by ball milling and
subsequent annealing. By milling, the Na3InCl6–xBrx solid
solution series crystallizes in a monoclinic P21/n phase,
while the subsequently annealed Na3InCl6–xBrx series
transforms into a trigonal P3̅1c phase. Through annealing
and changes of the structure type, greater anion solubility
can be achieved. The halide substitution slightly improves
the ionic conductivity in the Na3InCl6–xBrx series,
indicating that mixed halide compositions and their
structural changes affect the ionic transport albeit less
strongly than in the lithium analogues such as
Li3YCl6–xBrx and Li3InCl6–xBrx.},
cin = {IEK-12},
ddc = {540},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {1221 - Fundamentals and Materials (POF4-122)},
pid = {G:(DE-HGF)POF4-1221},
typ = {PUB:(DE-HGF)16},
pubmed = {37466299},
UT = {WOS:001032178200001},
doi = {10.1021/acs.inorgchem.3c01579},
url = {https://juser.fz-juelich.de/record/1009697},
}