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@ARTICLE{Bui:1014692,
author = {Bui, Minh N. and Rost, Stefan and Auge, Manuel and Zhou,
Lanqing and Friedrich, Christoph and Blügel, Stefan and
Kretschmer, Silvan and Krasheninnikov, Arkady V. and
Watanabe, Kenji and Taniguchi, Takashi and Hofsäss, Hans C.
and Grützmacher, Detlev and Kardynal, Beata},
title = {{O}ptical {P}roperties of {M}o{S}e 2 {M}onolayer
{I}mplanted with {U}ltra-{L}ow-{E}nergy {C}r {I}ons},
journal = {ACS applied materials $\&$ interfaces},
volume = {15},
number = {29},
issn = {1944-8244},
address = {Washington, DC},
publisher = {Soc.},
reportid = {FZJ-2023-03397},
pages = {35321 - 35331},
year = {2023},
abstract = {This paper explores the optical properties of an exfoliated
MoSe2 monolayer implanted with Cr+ ions, accelerated to 25
eV. Photoluminescence of the implanted MoSe2 reveals an
emission line from Cr-related defects that is present only
under weak electron doping. Unlike band-to-band transition,
the Cr-introduced emission is characterized by nonzero
activation energy, long lifetimes, and weak response to the
magnetic field. To rationalize the experimental results and
get insights into the atomic structure of the defects, we
modeled the Cr-ion irradiation process using ab initio
molecular dynamics simulations followed by the electronic
structure calculations of the system with defects. The
experimental and theoretical results suggest that the
recombination of electrons on the acceptors, which could be
introduced by the Cr implantation-induced defects, with the
valence band holes is the most likely origin of the
low-energy emission. Our results demonstrate the potential
of low-energy ion implantation as a tool to tailor the
properties of two-dimensional (2D) materials by doping.},
cin = {PGI-9 / PGI-1},
ddc = {600},
cid = {I:(DE-Juel1)PGI-9-20110106 / I:(DE-Juel1)PGI-1-20110106},
pnm = {5224 - Quantum Networking (POF4-522)},
pid = {G:(DE-HGF)POF4-5224},
typ = {PUB:(DE-HGF)16},
pubmed = {37432886},
UT = {WOS:001027014400001},
doi = {10.1021/acsami.3c05366},
url = {https://juser.fz-juelich.de/record/1014692},
}