Home > Publications database > Novel air-electrode materials for low-cost inert-supported solid oxide cells: investigation of materials compatibility during co-sintering > print |
001 | 1014797 | ||
005 | 20240711085632.0 | ||
024 | 7 | _ | |a 10.1007/s10853-023-08862-0 |2 doi |
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100 | 1 | _ | |a Juckel, Martin |0 P:(DE-Juel1)189092 |b 0 |e Corresponding author |u fzj |
245 | _ | _ | |a Novel air-electrode materials for low-cost inert-supported solid oxide cells: investigation of materials compatibility during co-sintering |
260 | _ | _ | |a Dordrecht [u.a.] |c 2023 |b Springer Science + Business Media B.V |
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520 | _ | _ | |a For the investigation of the reactivity of alternative solid oxide cell air electrode materials with forsterite (Mg2SiO4), a magnesium silicate doped with Zn and Ca, five different phase materials were chosen: two Ruddlesden–Popper phase materials: La4Ni3O10 (L4N3) and La3Ni2O7 (L3N2) and three titanium-based perovskite materials: SrTiO3 (STO), SrTi0.75Fe0.25O3 (STF25) and CaTi0.9Fe0.1O3 (CTF). Forsterite was chosen as a support material for the fuel cell, as it is abundant and therefore relatively inexpensive. For the investigation of their reactivity, different types of samples were prepared: mixed pellets, double-layered pellets and screen-printed electrode inks on forsterite green substrates, which were subsequently co-sintered at T = 1300 °C. These samples and their cross sections were then studied using XRD, SEM, EDS and TEM lamella point analysis. Consequently, the impedance spectra were acquired to determine their electro-catalytic performance. The two Ruddlesden–Popper phase materials L4N3 and L3N2 are of high interest due to their thermodynamic stability and high electro-catalytic activity, resulting in a very low polarization resistance. However, this polarization resistance is increased when mixing with forsterite material. In case of the three titanium-based perovskites, the electro-catalytic activity is of less interest due to high polarization resistances. |
536 | _ | _ | |a 1231 - Electrochemistry for Hydrogen (POF4-123) |0 G:(DE-HGF)POF4-1231 |c POF4-123 |f POF IV |x 0 |
536 | _ | _ | |a SOFC - Solid Oxide Fuel Cell (SOFC-20140602) |0 G:(DE-Juel1)SOFC-20140602 |c SOFC-20140602 |f SOFC |x 1 |
588 | _ | _ | |a Dataset connected to DataCite |
700 | 1 | _ | |a Grimm, Fabian |0 P:(DE-Juel1)171661 |b 1 |
700 | 1 | _ | |a Zischke, S. |0 P:(DE-HGF)0 |b 2 |
700 | 1 | _ | |a Sohn, Yoo Jung |0 P:(DE-Juel1)159368 |b 3 |u fzj |
700 | 1 | _ | |a Guillon, Olivier |0 P:(DE-Juel1)162228 |b 4 |u fzj |
700 | 1 | _ | |a Menzler, Norbert H. |0 P:(DE-Juel1)129636 |b 5 |u fzj |
773 | _ | _ | |a 10.1007/s10853-023-08862-0 |g Vol. 58, no. 34, p. 13705 - 13720 |0 PERI:(DE-600)2015305-3 |n 34 |p 13705 - 13720 |t Journal of materials science |v 58 |y 2023 |x 0022-2461 |
856 | 4 | _ | |u https://juser.fz-juelich.de/record/1014797/files/s10853-023-08862-0.pdf |y OpenAccess |
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