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@PHDTHESIS{Karim:10152,
author = {Karim, Kamran Said},
title = {{H}erstellung polykristalliner {S}zintillatoren für die
{P}ositronen-{E}missions-{T}omographie ({PET})},
volume = {55},
issn = {1866-1793},
school = {Univ. Bochum},
type = {Dr. (Univ.)},
address = {Jülich},
publisher = {Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag},
reportid = {PreJuSER-10152},
isbn = {978-3-89336-610-1},
series = {Schriften des Forschungszentrums Jülich : Energie $\&$
Umwelt / Energy $\&$ Environment},
pages = {VI, 154 S.},
year = {2010},
note = {Record converted from VDB: 12.11.2012; Univ. Bochum, Diss.,
2010},
abstract = {Transparent ceramics are becoming more and more important
for two new types of applications. On the one hand in cases
where high mechanical and thermal demands in combination
with optical properties are required, on the other hand
where the optical properties of transparent materials like
glass are not sufficient e.g. in positronemission-tomography
(PET) diagnostics. Most state of the art PET-scanners are
using high-priced single crystals as scintillator material.
The technological challenge is to replace single crystal by
cost-efficient transparent ceramics. Producing transparent
ceramics is ordered in synthesis of the powders and in
manufacturing of these into transparent ceramics. The aim of
this work was to synthesize single phase yttrium-alumina-and
Luthetiumalumina- garnet (YAG, LuAG) powders partially doped
with neodymium or praseodymium by four different synthesis
routes (Pechini-synthesis, sol-gel-route, coprecipitation
and solid state reactions). Additionally industrial LuAG and
LuPO4 powders were characterized and manufactured. The
powders were processed as submicron- and nanopowders. Newly
produced single-phase powders were homgenized with additions
of sintering additives like tetraethyl orthosilicate (TEOS)
and binders like polyvinyl alcohol (PVA). Moulding the
powders were carried out by unaxial pressing, cold isostatic
pressing and in individual cases also by slip casting. The
achieved green densities were in a range of 25-42 $\%.$
Examination of calcination behaviour leads to a calcination
temperature of 1000 °C with 2 hours dwell time in air
atmosphere. Only solid state reactions resulted into
transparent YAG, YAG:Pr, LuAG, LuAG:Pr ceramics. Solid state
reactions of nanopowders resulted in heterogeneously
transparent samples. Ceramics made by powders of other
synthetic routes gave nontransparent ceramics due to
porosity and additional phases. Transmission measurements of
the manufactured transparent ceramics showed in classical
one step sintering and two step sintering program
significant lower transmission than respectitive single
crystals but similar transmission compared to ceramics
reported in literature.},
cin = {IEF-1},
ddc = {333.7},
cid = {I:(DE-Juel1)VDB809},
pnm = {Rationelle Energieumwandlung},
pid = {G:(DE-Juel1)FUEK402},
typ = {PUB:(DE-HGF)11 / PUB:(DE-HGF)3},
url = {https://juser.fz-juelich.de/record/10152},
}