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@ARTICLE{Hodges:1017075,
author = {Hodges, Aaron and Renz, Stefanie and Lohmann-Richters,
Felix and Al-Musawi, Atheer and Jupke, Andreas and Lehnert,
Werner and Swiegers, Gerhard F. and Wallace, Gordon G.},
title = {{C}ritical {A}nalysis of {P}ublished {P}hysical {P}roperty
{D}ata for {A}queous {P}otassium {H}ydroxide. {C}ollation
into {D}etailed {M}odels for {A}lkaline {E}lectrolysis},
journal = {Journal of chemical $\&$ engineering data},
volume = {68},
number = {7},
issn = {0021-9568},
address = {Columbus, Ohio},
publisher = {American Chemical Society},
reportid = {FZJ-2023-03917},
pages = {1485 - 1506},
year = {2023},
abstract = {Physical properties of aqueous KOH solutions are crucial to
the design and operation of alkaline electrolyzers but have
been scarcely and sometimes unreliably reported. Obtaining
published data for various properties currently requires
time-consuming searches and subsequent interpretation,
interpolation, and extrapolation. This work collates and
critically analyzes published data for a range of physical
properties relevant to alkaline electrolysis, including the
density, viscosity, conductivity, surface tension,
oxygen/hydrogen solubility, oxygen/hydrogen diffusivity, and
water vapor pressures of aqueous KOH solutions, as a
function of temperature, KOH molarity, and pressure.
Correlation functions, in the form of excel spreadsheets,
have been developed to allow interpolation of the most
reliable data and computation of desired quantities at
specific temperatures, pressures, and KOH concentrations.
Composite models incorporating these properties have been
developed for automated computation of (i) diffusive gas
crossover and (ii) gas production volumes, including (iii)
water vapor content, and associated (iv) dissolved gas
concentrations in the liquid electrolyte, as a function of
KOH concentration, temperature, pressure, current density,
and separator thickness and porosity. These spreadsheets are
provided in the Supporting Information, as tools and
reference points for researchers and practitioners in
alkaline electrolysis.},
cin = {IEK-14},
ddc = {660},
cid = {I:(DE-Juel1)IEK-14-20191129},
pnm = {1231 - Electrochemistry for Hydrogen (POF4-123)},
pid = {G:(DE-HGF)POF4-1231},
typ = {PUB:(DE-HGF)16},
UT = {WOS:001018075900001},
doi = {10.1021/acs.jced.3c00040},
url = {https://juser.fz-juelich.de/record/1017075},
}