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@ARTICLE{Schlautmann:1017338,
author = {Schlautmann, Eva and Weiß, Alexander and Maus, Oliver and
Ketter, Lukas and Rana, Moumita and Puls, Sebastian and
Nickel, Vera and Gabbey, Christine and Hartnig, Christoph
and Bielefeld, Anja and Zeier, Wolfgang G.},
title = {{I}mpact of the {S}olid {E}lectrolyte {P}article {S}ize
{D}istribution in {S}ulfide‐{B}ased {S}olid‐{S}tate
{B}attery {C}omposites},
journal = {Advanced energy materials},
volume = {13},
number = {41},
issn = {1614-6832},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2023-04050},
pages = {2302309},
year = {2023},
abstract = {All solid-state batteries are promising, as they are
expected to offer increased energy density over conventional
lithium-ion batteries. Here, the microstructure of solid
composite electrodes plays a crucial role in determining the
characteristics of ionic and electronic pathways.
Microstructural aspects that impede charge carrier transport
can, for instance, be voids resulting from a general
mismatch of particle sizes. Solid electrolyte materials with
smaller particle size distribution represent a promising
approach to limit the formation of voids and to match the
smaller active materials. Therefore, a systematic
investigation on the influence of the solid electrolyte
particle size on the microstructural properties, charge
carrier transport, and rate performance is essential. This
study provides an understanding of the influence of the
particle sizes of Li6PS5Cl on the charge carrier transport
properties and their effect on the performance of
solid-state batteries. In conclusion, smaller Li6PS5Cl
particles optimize the charge transport properties and offer
a higher interface area with the active material, resulting
in improved solid-state battery performance.},
cin = {IEK-12},
ddc = {050},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {1221 - Fundamentals and Materials (POF4-122)},
pid = {G:(DE-HGF)POF4-1221},
typ = {PUB:(DE-HGF)16},
UT = {WOS:001070485800001},
doi = {10.1002/aenm.202302309},
url = {https://juser.fz-juelich.de/record/1017338},
}