% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@INBOOK{Mller:1017532,
      author       = {Müller, David},
      title        = {{NAP}-{XPS} {S}tudies of {M}ixed {C}onducting {E}lectrodes
                      {D}uring {H}igh-{T}emperature {E}lectrochemical {R}eactions},
      volume       = {21},
      address      = {London},
      publisher    = {WORLD SCIENTIFIC (EUROPE)},
      reportid     = {FZJ-2023-04181},
      isbn         = {978-1-80061-328-7 (print)},
      series       = {Catalytic Science Series},
      pages        = {457-499},
      year         = {2023},
      comment      = {Applications of X-ray Photoelectron Spectroscopy to
                      Catalytic Studies / Zafeiratos, Spyridon {CNRSFrance |
                      University of StrasbourgFrance} ; : WORLD SCIENTIFIC
                      (EUROPE), 2023, ; ISSN: 1793-1398=2399-4495 ; ISBN:
                      978-1-80061-328-7=978-1-80061-329-4 ; doi:10.1142/q0392},
      booktitle     = {Applications of X-ray Photoelectron
                       Spectroscopy to Catalytic Studies /
                       Zafeiratos, Spyridon {CNRSFrance |
                       University of StrasbourgFrance} ; :
                       WORLD SCIENTIFIC (EUROPE), 2023, ;
                       ISSN: 1793-1398=2399-4495 ; ISBN:
                       978-1-80061-328-7=978-1-80061-329-4 ;
                       doi:10.1142/q0392},
      abstract     = {In this chapter, we will give an overview of how NAP-XPS
                      can be used to investigate processes in and properties of
                      mixed ionic electronic conducting materials at elevated
                      temperatures, with a special focus on operando studies on
                      working electrochemical devices. After a brief introduction
                      of fundamental concepts of solid-state electroand defect
                      chemistry, we will focus on the reactions of prototypical
                      materials exposed to thermal, chemical, and electric stimuli
                      and how those can be elucidated with NAP-XPS. After
                      discussing the experimental challenges and general setups
                      used, we use examples to showcase the capabilities of
                      NAP-XPS. Starting with simple oxides, such as CeO2, where
                      NAP-XPS is used to clarify mechanisms of electrocatalytic
                      reactions with H2O and O2, we give several examples of how
                      the technique was used to significantly improve the
                      understanding of mixed conductors, the results themselves
                      being used to further drive technique development. NAP-XPS
                      shines brightly here, as surface-sensitive assessment of
                      both electrostatic as well as chemical properties is
                      unrivaled by any other technique. We extend the discussion
                      to more complex multicomponent transition metal perovskites
                      used in both cathodes and anodes of high-temperature
                      electrochemical devices, here the element and chemical state
                      sensitivity of NAP-XPS allows us to track atomic
                      rearrangements on the surface induced by changes in
                      electrochemical potentials, finishing with a short
                      description of NAP-XPS experiments on cermets, a special
                      case of a mixed conductor. This chapter is both intended for
                      the solid-state (electro)chemist to showcase how NAP-XPS
                      might help them to tackle physicochemical questions, as well
                      as to introduce the basic concepts of solid-state ionics and
                      electrochemistry to the spectroscopist, aiming to further
                      the understanding between those two fields.},
      cin          = {PGI-6},
      cid          = {I:(DE-Juel1)PGI-6-20110106},
      pnm          = {632 - Materials – Quantum, Complex and Functional
                      Materials (POF4-632) / DFG project 319443528 -
                      Magnetfeldunterstützte chemische Gasphasenabscheidung von
                      Übergansmetalloxiden und in situ Untersuchungen der
                      elektronischen Struktur mit Hilfe von
                      Roentgenabsorptionsspektroskopie (MagSpec) (319443528)},
      pid          = {G:(DE-HGF)POF4-632 / G:(GEPRIS)319443528},
      typ          = {PUB:(DE-HGF)7},
      url          = {https://juser.fz-juelich.de/record/1017532},
}