Gast ::
| Hauptseite > Publikationsdatenbank > Thermal and combined high-temperature and high-pressure behavior of a natural intermediate scapolite > print |
| Hauptseite > Publikationsdatenbank > Thermal and combined high-temperature and high-pressure behavior of a natural intermediate scapolite > print |
| 001 | 1018015 | ||
| 005 | 20250320202214.0 | ||
| 024 | 7 | _ | |a 10.2138/am-2023-8962 |2 doi |
| 024 | 7 | _ | |a 0003-004X |2 ISSN |
| 024 | 7 | _ | |a 1945-3027 |2 ISSN |
| 024 | 7 | _ | |a 10.34734/FZJ-2023-04485 |2 datacite_doi |
| 024 | 7 | _ | |a WOS:001155433300013 |2 WOS |
| 037 | _ | _ | |a FZJ-2023-04485 |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Lotti |0 P:(DE-HGF)0 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Thermal and combined high-temperature and high-pressure behavior of a natural intermediate scapolite |
| 260 | _ | _ | |a Alexandria, Va. |c 2024 |b GeoScienceWorld |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1742474272_16428 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a A natural intermediate member of the scapolite solid solution (Me$_{47}$; experimental chemical formula: (Na$_{1.86}$Ca$_{1.86}$K$_{0.23}$Fe$_{0.01}$)(Al$_{4.36}$Si$_{7.64}$)O$_{24}$[Cl$_{0.48}$(CO$_3$)$_{0.48}$(SO$_4$)$_{0.01}$]), with the unusual I4/m space group, has been studied at various temperatures and combined high-$T$ and high-$P$ by means of in situ single-crystal and powder X-ray diffraction, at both conventional and synchrotron sources. In addition, single-crystal neutron diffraction data were collected at ambient-T and 685 °C. A fit of the experimental V-T data with a thermal equation of state yielded a calculated thermal expansion coefficient at ambient conditions: $α_{V25°C} = 1/V_0·(∂V/∂T)_{P,25°C} = 1.74(3)·10^{-5}$ K$^{-1}$. A comparative analysis of the elastic behavior of scapolite based on this study and other high-$T$ XRD data reported in the literature suggests that a thorough re-investigation of the different members of the marialite-meionite solid solution is needed to fully understand the role of crystal chemistry on the thermal behavior of these complex non-binary solid solutions. The experimental data obtained within the full temperature range of analysis at ambient pressure confirm that the investigated sample always preserves the I4/m space group, and possible implications on the metastability of I4/m intermediate scapolite are discussed. Neutron diffraction data show that no significant Si and Al re-arrangement among the T sites occurs between 25 and 685 °C. The combined high-$T$ and high-$P$ data show that at 650 °C and between 10.30(5) and 10.71(5) GPa a phase transition towards a triclinic polymorph occurs, with a positive Clapeyron slope (i.e., $dP/dT > 0$). A comprehensive description of the atomic-scale structure deformation mechanisms induced by temperature and/or pressure, including those leading to structural instability, is provided based on single-crystal structure refinements. |
| 536 | _ | _ | |a 6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ) (POF4-6G4) |0 G:(DE-HGF)POF4-6G4 |c POF4-6G4 |f POF IV |x 0 |
| 536 | _ | _ | |a CALIPSOplus - Convenient Access to Light Sources Open to Innovation, Science and to the World (730872) |0 G:(EU-Grant)730872 |c 730872 |f H2020-INFRAIA-2016-1 |x 1 |
| 588 | _ | _ | |a Dataset connected to CrossRef, Journals: juser.fz-juelich.de |
| 650 | 2 | 7 | |a Crystallography |0 V:(DE-MLZ)SciArea-240 |2 V:(DE-HGF) |x 0 |
| 650 | 2 | 7 | |a Geosciences |0 V:(DE-MLZ)SciArea-140 |2 V:(DE-HGF) |x 1 |
| 650 | 2 | 7 | |a Chemistry |0 V:(DE-MLZ)SciArea-110 |2 V:(DE-HGF) |x 2 |
| 650 | 1 | 7 | |a Earth, Environment and Cultural Heritage |0 V:(DE-MLZ)GC-170-2016 |2 V:(DE-HGF) |x 0 |
| 693 | _ | _ | |a Forschungs-Neutronenquelle Heinz Maier-Leibnitz |e HEiDi: Single crystal diffractometer on hot source |f SR9b |1 EXP:(DE-MLZ)FRMII-20140101 |0 EXP:(DE-MLZ)HEIDI-20140101 |5 EXP:(DE-MLZ)HEIDI-20140101 |6 EXP:(DE-MLZ)SR9b-20140101 |x 0 |
| 693 | _ | _ | |a PETRA III |f PETRA Beamline P02.2 |1 EXP:(DE-H253)PETRAIII-20150101 |0 EXP:(DE-H253)P-P02.2-20150101 |6 EXP:(DE-H253)P-P02.2-20150101 |x 1 |
| 700 | 1 | _ | |a Gatta, Diego G. |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Gigli, Lara |0 P:(DE-HGF)0 |b 2 |
| 700 | 1 | _ | |a Krüger, Hannes |0 P:(DE-HGF)0 |b 3 |
| 700 | 1 | _ | |a Kahlenberg, Volker |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Meven, Martin |0 P:(DE-HGF)0 |b 5 |
| 700 | 1 | _ | |a Comoni, Davide |0 P:(DE-HGF)0 |b 6 |
| 700 | 1 | _ | |a Milani, Sula |0 P:(DE-HGF)0 |b 7 |
| 700 | 1 | _ | |a Merlini, Marco |0 P:(DE-HGF)0 |b 8 |
| 700 | 1 | _ | |a Liermann, Hanns Peter |0 P:(DE-HGF)0 |b 9 |
| 773 | _ | _ | |a 10.2138/am-2023-8962 |0 PERI:(DE-600)2045960-9 |n 2 |p 243–254 |t American mineralogist |v 109 |y 2024 |x 0003-004X |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/1018015/files/10.2138_am-2023-8962.pdf |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/1018015/files/8962LottiPreprint.pdf |y OpenAccess |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/1018015/files/10.2138_am-2023-8962.gif?subformat=icon |x icon |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/1018015/files/10.2138_am-2023-8962.jpg?subformat=icon-1440 |x icon-1440 |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/1018015/files/10.2138_am-2023-8962.jpg?subformat=icon-180 |x icon-180 |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/1018015/files/10.2138_am-2023-8962.jpg?subformat=icon-640 |x icon-640 |y Restricted |
| 909 | C | O | |o oai:juser.fz-juelich.de:1018015 |p openaire |p open_access |p driver |p VDB:MLZ |p VDB |p ec_fundedresources |p dnbdelivery |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 0 |6 P:(DE-HGF)0 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 1 |6 P:(DE-HGF)0 |
| 910 | 1 | _ | |a RWTH Aachen |0 I:(DE-588b)36225-6 |k RWTH |b 5 |6 P:(DE-HGF)0 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 5 |6 P:(DE-HGF)0 |
| 910 | 1 | _ | |a Heinz Maier-Leibnitz Zentrum |0 I:(DE-588b)4597118-3 |k MLZ |b 5 |6 P:(DE-HGF)0 |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Materie |l Großgeräte: Materie |1 G:(DE-HGF)POF4-6G0 |0 G:(DE-HGF)POF4-6G4 |3 G:(DE-HGF)POF4 |2 G:(DE-HGF)POF4-600 |4 G:(DE-HGF)POF |v Jülich Centre for Neutron Research (JCNS) (FZJ) |x 0 |
| 914 | 1 | _ | |y 2024 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0160 |2 StatID |b Essential Science Indicators |d 2023-10-24 |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0113 |2 StatID |b Science Citation Index Expanded |d 2023-10-24 |
| 915 | _ | _ | |a OpenAccess |0 StatID:(DE-HGF)0510 |2 StatID |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |d 2025-01-02 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |d 2025-01-02 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0600 |2 StatID |b Ebsco Academic Search |d 2025-01-02 |
| 915 | _ | _ | |a Peer Review |0 StatID:(DE-HGF)0030 |2 StatID |b ASC |d 2025-01-02 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Clarivate Analytics Master Journal List |d 2025-01-02 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |d 2025-01-02 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |d 2025-01-02 |
| 920 | _ | _ | |l yes |
| 920 | 1 | _ | |0 I:(DE-Juel1)JCNS-FRM-II-20110218 |k JCNS-FRM-II |l JCNS-FRM-II |x 0 |
| 920 | 1 | _ | |0 I:(DE-82)080009_20140620 |k JARA-FIT |l JARA-FIT |x 1 |
| 920 | 1 | _ | |0 I:(DE-Juel1)JCNS-2-20110106 |k JCNS-2 |l Streumethoden |x 2 |
| 920 | 1 | _ | |0 I:(DE-588b)4597118-3 |k MLZ |l Heinz Maier-Leibnitz Zentrum |x 3 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a I:(DE-Juel1)JCNS-FRM-II-20110218 |
| 980 | _ | _ | |a I:(DE-82)080009_20140620 |
| 980 | _ | _ | |a I:(DE-Juel1)JCNS-2-20110106 |
| 980 | _ | _ | |a I:(DE-588b)4597118-3 |
| 980 | _ | _ | |a UNRESTRICTED |
| 980 | 1 | _ | |a FullTexts |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|