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001018146 1001_ $$00000-0003-4731-9097$$aSanchez-Garcia, Ivan$$b0$$eCorresponding author
001018146 245__ $$aInterinstitutional Study of the New EURO-GANEX Process Resistance by Gamma Irradiation Test Loops
001018146 260__ $$aColumbus, Ohio$$bAmerican Chemical Society$$c2023
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001018146 520__ $$aAs part of the homogeneous actinide recycling strategy, the EUROGANEXprocess is one of the most promising options to achieve the goal of minoractinides recovery. Improvements made to EURO-GANEX system have resulted in theemergence of the so-called New EURO-GANEX process, where the composition of thesolvent has been modified by replacing TODGA and DMDOHEMA with cismTDDGAin the organic phase and SO3-Ph-BTP with PyTri-Diol in the aqueousphase in order to resolve important issues. The objective of this work is 2-fold: evaluatethe gamma radiolytic resistance of the new EURO-GANEX process by dynamicirradiation conditions simulating the three main steps of the process and validate thedesign of CIEMAT Náyade, CEA Marcel, and INL irradiation loop devices since eachof them mimics different aspects of the real process. The Náyade and INL loops couldirradiate the organic and aqueous phases together, whereas in the CEA loop, theirradiated solvent is recycled continuously inside a platform with several stages ofmixer-settlers containing aqueous flows simulating the three main steps of the process. The extraction performances and changes inthe composition of the solvent have been analyzed during the irradiation experiment by different techniques: gamma spectrometryand ICP-MS/OES for cations or radioactive tracer extraction and HPLC-MS to identify and quantify the degradation compounds.Despite some differences between the three irradiation facilities, this interinstitutional study shows that these three comparative toolsprovide similar trends in the radiolytic stability of a liquid−liquid extraction system. Favorable extraction results for the differentsteps are obtained according to the static irradiation studies found in literature. However, the degradation of cis-mTDDGA isappreciable leading to degradation compounds, some of which form precipitates and produce important changes in viscosity,important aspects that must be addressed prior to the successful industrial application of the new EURO-GANEX process.
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001018146 7001_ $$0P:(DE-HGF)0$$aHeres, Xavier$$b1
001018146 7001_ $$00000-0003-4374-6948$$aPeterman, Dean. R.$$b2
001018146 7001_ $$0P:(DE-HGF)0$$aGalan, Hitos$$b3
001018146 7001_ $$0P:(DE-HGF)0$$aCostenoble, Sylvain$$b4
001018146 7001_ $$0P:(DE-HGF)0$$aBroussard, Sylvain$$b5
001018146 7001_ $$0P:(DE-HGF)0$$aSinot, Johann$$b6
001018146 7001_ $$00000-0003-2751-0492$$aGrimes, Travis S.$$b7
001018146 7001_ $$0P:(DE-HGF)0$$aAnderson, Kash Reid$$b8
001018146 7001_ $$00000-0002-0690-5957$$aJansone-Popova, Santa$$b9
001018146 7001_ $$0P:(DE-HGF)0$$aGullo, Maria Chiara$$b10
001018146 7001_ $$0P:(DE-HGF)0$$aCasnati, Alessandro$$b11
001018146 7001_ $$0P:(DE-Juel1)130438$$aWilden, Andreas$$b12
001018146 7001_ $$0P:(DE-HGF)0$$aGeist, Andreas$$b13
001018146 773__ $$0PERI:(DE-600)1484436-9$$a10.1021/acs.iecr.3c02884$$gp. acs.iecr.3c02884$$n47$$p20326–20339$$tIndustrial & engineering chemistry research$$v62$$x0888-5885$$y2023
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