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001018231 1001_ $$00000-0002-9348-8935$$aKozłowski, Paweł$$b0
001018231 245__ $$aMonoclinic symmetry of the hcp-type ordered areas in bulk cobalt
001018231 260__ $$aCollege Park, Maryland$$bAmerical Physical Society$$c2023
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001018231 520__ $$aThe gradual ferromagnetic spin reorientation in hexagonal close packed cobalt (hcp-Co) phase between 230 $^\circ$C and 330 $^\circ$C reported for a Co single crystal [Bertaut $\textit{et al.}$, Solid State Commun. $\textbf{1}$, 81 (1963)] suggests that this phase could not have a hexagonal symmetry. This hypothesis is verified positively by synchrotron radiation diffraction and neutron diffraction on polycrystalline powder cobalt. The analysis of diffraction data has been done by using a specific set of Bragg peaks, which are not sensitive to the stacking faults present in abundance in hcp-Co. The crystal structure of the hcp-type ordered areas of cobalt is described by the monoclinic symmetry with the magnetic space group $C2'/m'$. In this monoclinic crystal structure the former hexagonal $[001]$ axis is no longer perpendicular to the hexagonal layers. The hexagonal $[001]$ and $[010]$ axes make an angle equal $\alpha \approx 90.10(1)$ $^\circ$, while the angle between in-plane $[100]$ and $[010]$ axes equals $\gamma \approx 120.11(1)$ $^\circ$. The monoclinic symmetry provides an approximate description of the crystal structure of the stacking faulted hcp-Co areas coexisting with fcc-Co areas.
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001018231 7001_ $$0P:(DE-Juel1)201780$$aFabrykiewicz, Piotr$$b1
001018231 7001_ $$00000-0002-1574-7225$$aSosnowska, Izabela$$b2
001018231 7001_ $$00000-0001-9465-3106$$aFauth, François$$b3
001018231 7001_ $$00000-0002-1473-8992$$aSenyshyn, Anatoliy$$b4
001018231 7001_ $$00000-0001-5966-5929$$aSuard, Emmanuelle$$b5
001018231 7001_ $$00000-0002-7563-007X$$aOleszak, Dariusz$$b6
001018231 7001_ $$00000-0002-7550-6976$$aPrzeniosło, Radosław$$b7$$eCorresponding author
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