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@ARTICLE{NarayananKrishnamoorthy:1019516,
author = {Narayanan Krishnamoorthy, Anand and Wölke, Christian and
Diddens, Diddo and Maiti, Moumita and Mabrouk, Youssef and
Yan, Peng and Grünebaum, Mariano and Winter, Martin and
Heuer, Andreas and Cekic-Laskovic, Isidora},
title = {{D}ata‐{D}riven {A}nalysis of {H}igh‐{T}hroughput
{E}xperiments on {L}iquid {B}attery {E}lectrolyte
{F}ormulations: {U}nraveling the {I}mpact of {C}omposition
on {C}onductivity**},
journal = {Chemistry methods},
volume = {2},
number = {9},
issn = {2628-9725},
address = {Weinheim (Germany)},
publisher = {Wiley-VCH},
reportid = {FZJ-2023-05463},
pages = {e202200008},
year = {2022},
abstract = {A specially designed high-throughput experimentation
facility,used for the highly effective exploration of
electrolyte formulationsin composition space for diverse
battery chemistries andtargeted applications, is presented.
It follows a
high-throughputformulation-characterization-optimization
chain based on a setof previously established
electrolyte-related requirements. Here,the facility is used
to acquire large dataset of ionic conductivitiesof
non-aqueous battery electrolytes in the conducting
saltsolvent/co-solvent-additive composition space. The
measuredtemperature dependence is mapped on three
generalizedArrhenius parameters, including deviations from
simple activateddynamics. This reduced dataset is thereafter
analyzed bya scalable data-driven workflow, based on linear
and Gaussianprocess regression, providing detailed
information about thecompositional dependence of the
conductivity. Completeinsensitivity to the addition of
electrolyte additives for otherwiseconstant molar
composition is observed. Quantitativedependencies, for
example, on the temperature-dependentconducting salt content
for optimum conductivity are providedand discussed in light
of physical properties such as viscosityand ion association
effects.},
cin = {IEK-12},
ddc = {540},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {1222 - Components and Cells (POF4-122) / BIG-MAP - Battery
Interface Genome - Materials Acceleration Platform (957189)},
pid = {G:(DE-HGF)POF4-1222 / G:(EU-Grant)957189},
typ = {PUB:(DE-HGF)16},
UT = {WOS:001054525700004},
doi = {10.1002/cmtd.202200008},
url = {https://juser.fz-juelich.de/record/1019516},
}