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001019517 1001_ $$0P:(DE-HGF)0$$aJiang, Lihua$$b0
001019517 245__ $$aA nonflammable diethyl ethylphosphonate-based electrolyte improved by synergistic effect of lithium difluoro(oxalato)borate and fluoroethylene carbonate
001019517 260__ $$aNew York, NY [u.a.]$$bElsevier$$c2023
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001019517 520__ $$aThe vital physical and chemical properties of the lithium conducting salt, solvent/co-solvent and functionaladditive determine the overall properties and performance of the resulting electrolyte formulation. Explorationson right combinations of the carefully selected electrolyte components are expected to further balance theelectrochemical and safety performances of chosen electrolyte formulations in given cell chemistries. In thisstudy, a new nonaqueous aprotic electrolyte is designed by using lithium difluoro(oxalato)borate (LiODFB) asconducting salt, diethyl ethylphosphonate (DEEP) as solvent, and fluoroethylene carbonate (FEC) as co-solvent toachieve a nonflammable electrolyte formulation with competent electrochemical performance. The LiODFB andFEC are believed to take part in complex interfacial interactions with a synergistic effect. LiNi0.8Co0.1Mn0.1O2(NCM811)‖Li cells using the optimized electrolyte formulation of 1.3 M LiODFB/DEEP 30% FEC exhibits a stablelong-term cycling performance at 1.0 C with a reversible average specific discharge capacity of 169.5 mAh g
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001019517 7001_ $$0P:(DE-HGF)0$$aCheng, Yuan$$b1
001019517 7001_ $$0P:(DE-HGF)0$$aWang, Shuping$$b2$$eCorresponding author
001019517 7001_ $$0P:(DE-HGF)0$$aCheng, Yifeng$$b3
001019517 7001_ $$0P:(DE-HGF)0$$aJin, Kaiqiang$$b4
001019517 7001_ $$0P:(DE-HGF)0$$aSun, Jinhua$$b5
001019517 7001_ $$0P:(DE-Juel1)166130$$aWinter, Martin$$b6$$ufzj
001019517 7001_ $$0P:(DE-Juel1)171204$$aCekic-Laskovic, Isidora$$b7$$eCorresponding author
001019517 7001_ $$00000-0002-6686-195X$$aWang, Qingsong$$b8
001019517 773__ $$0PERI:(DE-600)1491915-1$$a10.1016/j.jpowsour.2023.233051$$gVol. 570, p. 233051 -$$p233051 -$$tJournal of power sources$$v570$$x0378-7753$$y2023
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