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001019520 0247_ $$2doi$$a10.1016/j.jpowsour.2022.232118
001019520 0247_ $$2ISSN$$a0378-7753
001019520 0247_ $$2ISSN$$a1873-2755
001019520 0247_ $$2datacite_doi$$a10.34734/FZJ-2023-05467
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001019520 1001_ $$0P:(DE-Juel1)179440$$aKühn, Sebastian P.$$b0
001019520 245__ $$aBack to the basics: Advanced understanding of the as-defined solid electrolyte interphase on lithium metal electrodes
001019520 260__ $$aNew York, NY [u.a.]$$bElsevier$$c2022
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001019520 520__ $$aThe design and control of the solid electrolyte interphase (SEI) is essential for the implementation ofrechargeable lithium metal based batteries and has been a major research theme of lithium metal electrodes forover 50 years. However, research on an as-defined SEI is challenging due to the inevitable presence of a nativepassivation layer (NPL), commonly contaminating an in situ formed SEI and its characteristics. Herein we presentan original study on an uncontaminated SEI being an exclusive reaction product of lithium and a liquid aproticelectrolyte, highlighting the largely negative influence of the NPL on different SEI characteristics and functionaladditive evaluation. A preformed as-defined SEI (pSEI) was generated by an in-house designed advanced pretreatmentmethod, ensuring high reproducibility and exclusion of the NPL by cutting and pressing lithiummetal in solution/electrolyte. The implementation of a pSEI allows for a systematic study and an uncloudedcomparison of the two common functional additives vinylene carbonate (VC) and fluoroethylene carbonate (FEC)in an equal molar setting. The introduction of an as-defined SEI allowed to clearly distinguish between enhancinginfluence on the SEI characteristics and full cell performance by FEC and the largely negative effect of VC ondifferent SEI characteristics.
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001019520 536__ $$0G:(BMBF)13XP0225C$$aLillint - Thermodynamic and kinetic stability of the Lithium-Liquid Electrolyte Interface (13XP0225C)$$c13XP0225C$$x1
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001019520 7001_ $$0P:(DE-Juel1)188450$$aPfeiffer, Felix$$b1
001019520 7001_ $$00000-0002-9741-2989$$aBela, Marlena$$b2
001019520 7001_ $$0P:(DE-Juel1)178947$$aRodehorst, Uta$$b3
001019520 7001_ $$0P:(DE-Juel1)190619$$aWeintz, Dominik$$b4$$ufzj
001019520 7001_ $$0P:(DE-Juel1)195878$$aStan, Marian$$b5$$ufzj
001019520 7001_ $$00000-0002-2754-6623$$aBaghernejad, Masoud$$b6
001019520 7001_ $$0P:(DE-Juel1)166130$$aWinter, Martin$$b7$$ufzj
001019520 7001_ $$0P:(DE-Juel1)171204$$aCekic-Laskovic, Isidora$$b8$$eCorresponding author
001019520 773__ $$0PERI:(DE-600)1491915-1$$a10.1016/j.jpowsour.2022.232118$$gVol. 549, p. 232118 -$$p232118 -$$tJournal of power sources$$v549$$x0378-7753$$y2022
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