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001     1019520
005     20240712113122.0
024 7 _ |a 10.1016/j.jpowsour.2022.232118
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024 7 _ |a 0378-7753
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024 7 _ |a 1873-2755
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024 7 _ |a 10.34734/FZJ-2023-05467
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037 _ _ |a FZJ-2023-05467
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100 1 _ |a Kühn, Sebastian P.
|0 P:(DE-Juel1)179440
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245 _ _ |a Back to the basics: Advanced understanding of the as-defined solid electrolyte interphase on lithium metal electrodes
260 _ _ |a New York, NY [u.a.]
|c 2022
|b Elsevier
336 7 _ |a article
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520 _ _ |a The design and control of the solid electrolyte interphase (SEI) is essential for the implementation ofrechargeable lithium metal based batteries and has been a major research theme of lithium metal electrodes forover 50 years. However, research on an as-defined SEI is challenging due to the inevitable presence of a nativepassivation layer (NPL), commonly contaminating an in situ formed SEI and its characteristics. Herein we presentan original study on an uncontaminated SEI being an exclusive reaction product of lithium and a liquid aproticelectrolyte, highlighting the largely negative influence of the NPL on different SEI characteristics and functionaladditive evaluation. A preformed as-defined SEI (pSEI) was generated by an in-house designed advanced pretreatmentmethod, ensuring high reproducibility and exclusion of the NPL by cutting and pressing lithiummetal in solution/electrolyte. The implementation of a pSEI allows for a systematic study and an uncloudedcomparison of the two common functional additives vinylene carbonate (VC) and fluoroethylene carbonate (FEC)in an equal molar setting. The introduction of an as-defined SEI allowed to clearly distinguish between enhancinginfluence on the SEI characteristics and full cell performance by FEC and the largely negative effect of VC ondifferent SEI characteristics.
536 _ _ |a 1222 - Components and Cells (POF4-122)
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536 _ _ |a Lillint - Thermodynamic and kinetic stability of the Lithium-Liquid Electrolyte Interface (13XP0225C)
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700 1 _ |a Pfeiffer, Felix
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700 1 _ |a Bela, Marlena
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700 1 _ |a Rodehorst, Uta
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700 1 _ |a Weintz, Dominik
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700 1 _ |a Stan, Marian
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700 1 _ |a Baghernejad, Masoud
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700 1 _ |a Winter, Martin
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700 1 _ |a Cekic-Laskovic, Isidora
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773 _ _ |a 10.1016/j.jpowsour.2022.232118
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856 4 _ |u https://juser.fz-juelich.de/record/1019520/files/Manuscript%20JPS.docx
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