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@INPROCEEDINGS{Pape:1019581,
author = {Pape, Sharon and Keller, Roger and Seidler, Florian and
Müller, Martin and Mechler, Anna and Lohmann-Richters,
Felix},
title = {{D}egradation {A}ssessment for {D}ynamic {O}peration of
{A}lkaline {E}lectrolysis {P}owered by {R}enewable {E}nergy},
reportid = {FZJ-2023-05516},
year = {2023},
abstract = {Alkaline water electrolysis is considered a core technology
for producing hydrogen on a large scale using renewable
energy. Renewable energies characteristically exhibit a
fluctuating and highly dynamic behavior. However,
conventional electrolyzers are designed to operate under
constant process conditions. To couple alkaline water
electrolysis with renewable energy, efforts are needed to
understand how dynamic operation impacts the durability of
the electrolysis system.This work aims to evaluate the
influence of intermittent operation on the durability of an
alkaline electrolyzer. Within this study, the behavior of
bare nickel electrodes responding to fluctuating potentials
was evaluated. Several influencing factors were evaluated to
investigate durability. Among these factors were various
load types such as the holding of the potential and the
cycling of the potential in triangular wave or square wave
(Figures 1a-c). Furthermore, the response to a renewable
energy input was investigated (Figure 1d). Ultimately, this
will allow to elucidate the relation between performance
losses during potential cycling and renewable load
profiles.Overall, the research is critical in understanding
how long-term performance will be affected as electrolysis
shifts to an intermittent renewable power supply. The
observations can provide metrics regarding future types and
degrees of operational load to limit performance loss and
can help assess long-term durability.},
month = {Jul},
date = {2023-07-04},
organization = {European Electrolyser and Fuel Cell
Forum 2023, Luzern (Switzerland), 4 Jul
2023 - 7 Jul 2023},
cin = {IEK-14 / IEK-9 / IEK-5},
cid = {I:(DE-Juel1)IEK-14-20191129 / I:(DE-Juel1)IEK-9-20110218 /
I:(DE-Juel1)IEK-5-20101013},
pnm = {1231 - Electrochemistry for Hydrogen (POF4-123)},
pid = {G:(DE-HGF)POF4-1231},
typ = {PUB:(DE-HGF)1},
doi = {10.34734/FZJ-2023-05516},
url = {https://juser.fz-juelich.de/record/1019581},
}