001020545 001__ 1020545
001020545 005__ 20240701202019.0
001020545 0247_ $$2doi$$a10.3390/polym15214303
001020545 0247_ $$2datacite_doi$$a10.34734/FZJ-2024-00258
001020545 0247_ $$2pmid$$a37959983
001020545 0247_ $$2WOS$$aWOS:001121079700001
001020545 037__ $$aFZJ-2024-00258
001020545 041__ $$aEnglish
001020545 082__ $$a540
001020545 1001_ $$0P:(DE-HGF)0$$aGiroto, Amanda S.$$b0$$eCorresponding author
001020545 245__ $$aRevealing the Structure Formation on Polyglycerol Citrate Polymers—An Environmentally Friendly Polyester as a Seed-Coating Material
001020545 260__ $$aBasel$$bMDPI$$c2023
001020545 3367_ $$2DRIVER$$aarticle
001020545 3367_ $$2DataCite$$aOutput Types/Journal article
001020545 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1719815445_31265
001020545 3367_ $$2BibTeX$$aARTICLE
001020545 3367_ $$2ORCID$$aJOURNAL_ARTICLE
001020545 3367_ $$00$$2EndNote$$aJournal Article
001020545 520__ $$aA detailed structural investigation of a promising bio-based polymer, polyglycerol citrate polyester, obtained by the bulk polycondensation of glycerol (Gly) against citric acid (Cit) under mild reaction was performed. The reaction in conditions with and without catalyst use (sulfuric acid, H2SO4) was investigated, showing evidence that it is possible to modify the polymer solubility according to the ratio and catalyst utilization. 13C and 1H NMR indicated that synthesis catalyzed with Cit excess leads to higher esterification degrees of citrate groups. In contrast, the Gly moieties are more prominent in catalyzed polymers regardless of the excess monomers. Overall, a successful conversion of Gly and Cit into polyesters was attained even without catalysis, enabling a simple route for the large-scale production of this green material to be used as a coating material. This polymer has been shown to be well-suited for coating seeds and might be a promising material for similar agricultural applications. Tests on soybean seed coating with a PGCit solution of 75% indicated that the seed quality and germination rate were not affected by the PGCit coating, concluding that this polymer is suitable for this application.
001020545 536__ $$0G:(DE-HGF)POF4-2172$$a2172 - Utilization of renewable carbon and energy sources and engineering of ecosystem functions (POF4-217)$$cPOF4-217$$fPOF IV$$x0
001020545 588__ $$aDataset connected to CrossRef, Journals: juser.fz-juelich.de
001020545 7001_ $$0P:(DE-HGF)0$$aValle, Stella F.$$b1
001020545 7001_ $$0P:(DE-HGF)0$$aBorges, Roger$$b2
001020545 7001_ $$0P:(DE-HGF)0$$aColnago, Luiz A.$$b3
001020545 7001_ $$0P:(DE-HGF)0$$aRibeiro, Tatiana S.$$b4
001020545 7001_ $$0P:(DE-Juel1)129475$$aJablonowski, Nicolai David$$b5$$eCorresponding author$$ufzj
001020545 7001_ $$0P:(DE-HGF)0$$aRibeiro, Caue$$b6$$eCorresponding author
001020545 7001_ $$0P:(DE-HGF)0$$aMattoso, Luiz H. C.$$b7
001020545 773__ $$0PERI:(DE-600)2527146-5$$a10.3390/polym15214303$$gVol. 15, no. 21, p. 4303 -$$n21$$p4303 -$$tPolymers$$v15$$x2073-4360$$y2023
001020545 8564_ $$uhttps://juser.fz-juelich.de/record/1020545/files/Giroto_ETAl_2023_polymers_Revealing%20the%20Structure%20Formation%20on%20Polyglycerol%20Citrate%20Polymers%E2%80%94An%20Environmentally%20Friendly%20Polyester%20as%20a%20Seed-Coating%20Material.pdf$$yOpenAccess
001020545 8564_ $$uhttps://juser.fz-juelich.de/record/1020545/files/Giroto_ETAl_2023_polymers_Revealing%20the%20Structure%20Formation%20on%20Polyglycerol%20Citrate%20Polymers%E2%80%94An%20Environmentally%20Friendly%20Polyester%20as%20a%20Seed-Coating%20Material.gif?subformat=icon$$xicon$$yOpenAccess
001020545 8564_ $$uhttps://juser.fz-juelich.de/record/1020545/files/Giroto_ETAl_2023_polymers_Revealing%20the%20Structure%20Formation%20on%20Polyglycerol%20Citrate%20Polymers%E2%80%94An%20Environmentally%20Friendly%20Polyester%20as%20a%20Seed-Coating%20Material.jpg?subformat=icon-1440$$xicon-1440$$yOpenAccess
001020545 8564_ $$uhttps://juser.fz-juelich.de/record/1020545/files/Giroto_ETAl_2023_polymers_Revealing%20the%20Structure%20Formation%20on%20Polyglycerol%20Citrate%20Polymers%E2%80%94An%20Environmentally%20Friendly%20Polyester%20as%20a%20Seed-Coating%20Material.jpg?subformat=icon-180$$xicon-180$$yOpenAccess
001020545 8564_ $$uhttps://juser.fz-juelich.de/record/1020545/files/Giroto_ETAl_2023_polymers_Revealing%20the%20Structure%20Formation%20on%20Polyglycerol%20Citrate%20Polymers%E2%80%94An%20Environmentally%20Friendly%20Polyester%20as%20a%20Seed-Coating%20Material.jpg?subformat=icon-640$$xicon-640$$yOpenAccess
001020545 8767_ $$d2024-02-05$$eAPC$$jZahlung erfolgt
001020545 909CO $$ooai:juser.fz-juelich.de:1020545$$pOpenAPC$$popen_access$$pdnbdelivery$$popenCost$$pVDB$$pdriver$$popenaire
001020545 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Embrapa Instrumentation, XV de Novembro Street, 1452, São Carlos 13560-970, SP, Brazil$$b1
001020545 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Embrapa Instrumentation, XV de Novembro Street, 1452, São Carlos 13560-970, SP, Brazil$$b2
001020545 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Embrapa Instrumentation, XV de Novembro Street, 1452, São Carlos 13560-970, SP, Brazil$$b3
001020545 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Department of Natural Science, Mathematics and Education, Federal University of São Carlos, Anhanguera, km 174, Araras 13604-900, SP, Brazil$$b4
001020545 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)129475$$aForschungszentrum Jülich$$b5$$kFZJ
001020545 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Embrapa Instrumentation, XV de Novembro Street, 1452, São Carlos 13560-970, SP, Brazil$$b6
001020545 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Embrapa Instrumentation, XV de Novembro Street, 1452, São Carlos 13560-970, SP, Brazil$$b7
001020545 9131_ $$0G:(DE-HGF)POF4-217$$1G:(DE-HGF)POF4-210$$2G:(DE-HGF)POF4-200$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF4-2172$$aDE-HGF$$bForschungsbereich Erde und Umwelt$$lErde im Wandel – Unsere Zukunft nachhaltig gestalten$$vFür eine nachhaltige Bio-Ökonomie – von Ressourcen zu Produkten$$x0
001020545 9141_ $$y2023
001020545 915pc $$0PC:(DE-HGF)0000$$2APC$$aAPC keys set
001020545 915pc $$0PC:(DE-HGF)0001$$2APC$$aLocal Funding
001020545 915pc $$0PC:(DE-HGF)0002$$2APC$$aDFG OA Publikationskosten
001020545 915pc $$0PC:(DE-HGF)0003$$2APC$$aDOAJ Journal
001020545 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2023-10-26
001020545 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
001020545 915__ $$0StatID:(DE-HGF)0501$$2StatID$$aDBCoverage$$bDOAJ Seal$$d2023-04-12T15:03:07Z
001020545 915__ $$0StatID:(DE-HGF)0500$$2StatID$$aDBCoverage$$bDOAJ$$d2023-04-12T15:03:07Z
001020545 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2023-10-26
001020545 915__ $$0StatID:(DE-HGF)0700$$2StatID$$aFees$$d2023-10-26
001020545 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
001020545 915__ $$0StatID:(DE-HGF)0561$$2StatID$$aArticle Processing Charges$$d2023-10-26
001020545 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bDOAJ : Anonymous peer review$$d2023-04-12T15:03:07Z
001020545 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bPOLYMERS-BASEL : 2022$$d2024-02-05
001020545 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2024-02-05
001020545 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2024-02-05
001020545 915__ $$0StatID:(DE-HGF)0320$$2StatID$$aDBCoverage$$bPubMed Central$$d2024-02-05
001020545 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search$$d2024-02-05
001020545 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC$$d2024-02-05
001020545 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2024-02-05
001020545 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2024-02-05
001020545 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2024-02-05
001020545 915__ $$0StatID:(DE-HGF)9905$$2StatID$$aIF >= 5$$bPOLYMERS-BASEL : 2022$$d2024-02-05
001020545 9201_ $$0I:(DE-Juel1)IBG-2-20101118$$kIBG-2$$lPflanzenwissenschaften$$x0
001020545 980__ $$ajournal
001020545 980__ $$aVDB
001020545 980__ $$aI:(DE-Juel1)IBG-2-20101118
001020545 980__ $$aAPC
001020545 980__ $$aUNRESTRICTED
001020545 9801_ $$aAPC
001020545 9801_ $$aFullTexts