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@ARTICLE{Vlkel:1020894,
author = {Völkel, Lukas and Braun, Dennis and Belete, Melkamu and
Kataria, Satender and Wahlbrink, Thorsten and Ran, Ke and
Kistermann, Kevin and Mayer, Joachim and Menzel, Stephan and
Daus, Alwin and Lemme, Max C.},
title = {{R}esistive {S}witching and {C}urrent {C}onduction
{M}echanisms in {H}exagonal {B}oron {N}itride {T}hreshold
{M}emristors with {N}ickel {E}lectrodes},
publisher = {arXiv},
reportid = {FZJ-2024-00370},
year = {2023},
abstract = {The two-dimensional (2D) insulating material hexagonal
boron nitride (h BN) has attracted much attention as the
active medium in memristive devices due to its favorable
physical properties, among others, a wide bandgap that
enables a large switching window. Metal filament formation
is frequently suggested for h-BN devices as the resistive
switching (RS) mechanism, usually supported by highly
specialized methods like conductive atomic force microscopy
(C-AFM) or transmission electron microscopy (TEM). Here, we
investigate the switching of multilayer hexagonal boron
nitride (h-BN) threshold memristors with two nickel (Ni)
electrodes through their current conduction mechanisms. Both
the high and the low resistance states are analyzed through
temperature-dependent current-voltage measurements. We
propose the formation and retraction of nickel filaments
along boron defects in the h-BN film as the resistive
switching mechanism. We corroborate our electrical data with
TEM analyses to establish temperature-dependent
current-voltage measurements as a valuable tool for the
analysis of resistive switching phenomena in memristors made
of 2D materials. Our memristors exhibit a wide and tunable
current operation range and low stand-by currents, in line
with the state of the art in h-BN-based threshold switches,
a low cycle-to-cycle variability of $5\%,$ and a large
On/Off ratio of 10${^7}$.},
keywords = {Applied Physics (physics.app-ph) (Other) / Materials
Science (cond-mat.mtrl-sci) (Other) / FOS: Physical sciences
(Other)},
cin = {PGI-7 / PGI-10 / JARA-FIT / ER-C-2},
cid = {I:(DE-Juel1)PGI-7-20110106 / I:(DE-Juel1)PGI-10-20170113 /
$I:(DE-82)080009_20140620$ / I:(DE-Juel1)ER-C-2-20170209},
pnm = {5233 - Memristive Materials and Devices (POF4-523) / BMBF
16ME0398K - Verbundprojekt: Neuro-inspirierte Technologien
der künstlichen Intelligenz für die Elektronik der Zukunft
- NEUROTEC II - (BMBF-16ME0398K)},
pid = {G:(DE-HGF)POF4-5233 / G:(DE-82)BMBF-16ME0398K},
typ = {PUB:(DE-HGF)25},
doi = {10.48550/ARXIV.2301.10158},
url = {https://juser.fz-juelich.de/record/1020894},
}