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@ARTICLE{Rezaeyan:1021481,
      author       = {Rezaeyan, Amirsaman and Kampman, Niko and Pipich, Vitaliy
                      and Barnsley, Lester C. and Rother, Gernot and Magill,
                      Clayton and Ma, Jingsheng and Busch, Andreas},
      title        = {{C}ompaction and clay content control mudrock porosity},
      journal      = {Energy},
      volume       = {289},
      issn         = {0360-5442},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2024-00774},
      pages        = {129966 -},
      year         = {2024},
      abstract     = {Mudrocks, ubiquitous yet poorly understood sedimentary
                      rocks with significant variations in composition and
                      physical properties, form seals for geological carbon
                      dioxide and energy (e.g., hydrogen and methane) storage,
                      repositories for radioactive waste disposal, and reservoirs
                      for natural gas. Understanding the controls on mudrock pore
                      structure is essential for evaluating their porosity. The
                      identification and quantification of controls depend on
                      the nano-to micron scale pore network, which are the subject
                      of this study. Small-angle (SANS) and very small-angle
                      neutron scattering (VSANS) experiments were conducted on 13
                      diverse mudrock sets, charac-terised by differences in
                      mineralogy, stratigraphy, maturity, and depositional
                      environment. We performed multivariate statistics to
                      systematically characterise the pore structure in 71 samples
                      cross a 5 μm–2 nm pore size range. Our results indicate a
                      multivariate approach more effectively captures the complex
                      controls on porosity rather than single parameters.
                      Compaction and clay content emerge as key primary and
                      secondary controls on mudrock porosity, respectively, upon
                      which we introduce a new porosity classification. Our
                      complementary experimental-statistical assessment involving
                      SANS-derived multiscale porosity sheds new light on the
                      influence of structural controls on storage or production
                      capacity in mudrocks.},
      cin          = {JCNS-FRM-II / JCNS-4 / MLZ / JCNS-1},
      ddc          = {600},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-4-20201012 / I:(DE-588b)4597118-3 /
                      I:(DE-Juel1)JCNS-1-20110106},
      pnm          = {6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ)
                      (POF4-6G4) / 632 - Materials – Quantum, Complex and
                      Functional Materials (POF4-632)},
      pid          = {G:(DE-HGF)POF4-6G4 / G:(DE-HGF)POF4-632},
      experiment   = {EXP:(DE-MLZ)KWS1-20140101 / EXP:(DE-MLZ)KWS3-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:001138055200001},
      doi          = {10.1016/j.energy.2023.129966},
      url          = {https://juser.fz-juelich.de/record/1021481},
}