001021595 001__ 1021595 001021595 005__ 20240709082123.0 001021595 0247_ $$2doi$$a10.1002/adfm.202304262 001021595 0247_ $$2ISSN$$a1616-301X 001021595 0247_ $$2ISSN$$a1057-9257 001021595 0247_ $$2ISSN$$a1099-0712 001021595 0247_ $$2ISSN$$a1616-3028 001021595 0247_ $$2datacite_doi$$a10.34734/FZJ-2024-00858 001021595 0247_ $$2WOS$$aWOS:001024900700001 001021595 037__ $$aFZJ-2024-00858 001021595 082__ $$a530 001021595 1001_ $$00000-0002-5022-9562$$aRocha-Ortiz, Juan S.$$b0$$eCorresponding author 001021595 245__ $$aEnhancing Planar Inverted Perovskite Solar Cells with Innovative Dumbbell‐Shaped HTMs: A Study of Hexabenzocoronene and Pyrene‐BODIPY‐Triarylamine Derivatives 001021595 260__ $$aWeinheim$$bWiley-VCH$$c2023 001021595 3367_ $$2DRIVER$$aarticle 001021595 3367_ $$2DataCite$$aOutput Types/Journal article 001021595 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1706013865_11732 001021595 3367_ $$2BibTeX$$aARTICLE 001021595 3367_ $$2ORCID$$aJOURNAL_ARTICLE 001021595 3367_ $$00$$2EndNote$$aJournal Article 001021595 520__ $$aDumbbell-shaped systems based on PAHs-BODIPY-triarylamine hybrids TM-(01-04) are designed as novel and highly efficient hole-transporting materials for usage in planar inverted perovskite solar cells. BODIPY is employed as a bridge between the PAH units, and the effects of the conjugated π-system's covalent attachment and size are investigated. Fluorescence quenching, 3D fluorescence heat maps, and theoretical studies support energy transfer within the moieties. The systems are extremely resistant to UVC 254 nm germicidal light sources and present remarkable thermal stability at degradation temperatures exceeding 350 °C. Integrating these systems into perovskite solar cells results in outstanding power conversion efficiency (PCE), with TM-02-based devices exhibiting a PCE of 20.26%. The devices base on TM-01, TM-03, and TM-04 achieve PCE values of 16.98%, 17.58%, and 18.80%, respectively. The long-term stability of these devices is measured for 600 h, with initial efficiency retention between 94% and 86%. The TM-04-based device presents noticeable stability of 94%, better than the reference polymer PTAA with 91%. These findings highlight the exciting potential of dumbbell-shaped systems based on PAHs-BODIPY-triarylamine derivatives for next-generation photovoltaics. 001021595 536__ $$0G:(DE-HGF)POF4-1213$$a1213 - Cell Design and Development (POF4-121)$$cPOF4-121$$fPOF IV$$x0 001021595 588__ $$aDataset connected to CrossRef, Journals: juser.fz-juelich.de 001021595 7001_ $$0P:(DE-Juel1)192542$$aWu, Jianchang$$b1$$ufzj 001021595 7001_ $$aWenzel, Jonas$$b2 001021595 7001_ $$aBornschlegl, Andreas J.$$b3 001021595 7001_ $$00000-0001-7669-7797$$aPerea, Jose Dario$$b4 001021595 7001_ $$00000-0002-2757-9417$$aLeon, Salvador$$b5 001021595 7001_ $$aBarabash, Anastasia$$b6 001021595 7001_ $$aWollny, Anna-Sophie$$b7 001021595 7001_ $$aGuldi, Dirk M.$$b8 001021595 7001_ $$0P:(DE-Juel1)194716$$aZhang, Jiyun$$b9$$ufzj 001021595 7001_ $$aInsuasty, Alberto$$b10 001021595 7001_ $$aLüer, Larry$$b11 001021595 7001_ $$aOrtiz, Alejandro$$b12 001021595 7001_ $$aHirsch, Andreas$$b13 001021595 7001_ $$0P:(DE-Juel1)176427$$aBrabec, Christoph$$b14$$eCorresponding author$$ufzj 001021595 773__ $$0PERI:(DE-600)2039420-2$$a10.1002/adfm.202304262$$gVol. 33, no. 44, p. 2304262$$n44$$p2304262$$tAdvanced functional materials$$v33$$x1616-301X$$y2023 001021595 8564_ $$uhttps://juser.fz-juelich.de/record/1021595/files/manuscript%206.2.docx$$yPublished on 2023-10-25. Available in OpenAccess from 2024-10-25. 001021595 909CO $$ooai:juser.fz-juelich.de:1021595$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire 001021595 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)192542$$aForschungszentrum Jülich$$b1$$kFZJ 001021595 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)194716$$aForschungszentrum Jülich$$b9$$kFZJ 001021595 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)176427$$aForschungszentrum Jülich$$b14$$kFZJ 001021595 9131_ $$0G:(DE-HGF)POF4-121$$1G:(DE-HGF)POF4-120$$2G:(DE-HGF)POF4-100$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF4-1213$$aDE-HGF$$bForschungsbereich Energie$$lMaterialien und Technologien für die Energiewende (MTET)$$vPhotovoltaik und Windenergie$$x0 001021595 9141_ $$y2023 001021595 915__ $$0StatID:(DE-HGF)0530$$2StatID$$aEmbargoed OpenAccess 001021595 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2023-10-24 001021595 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2023-10-24 001021595 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2023-10-24 001021595 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2023-10-24 001021595 915__ $$0StatID:(DE-HGF)1160$$2StatID$$aDBCoverage$$bCurrent Contents - Engineering, Computing and Technology$$d2023-10-24 001021595 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2023-10-24 001021595 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bADV FUNCT MATER : 2022$$d2023-10-24 001021595 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search$$d2023-10-24 001021595 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC$$d2023-10-24 001021595 915__ $$0StatID:(DE-HGF)9915$$2StatID$$aIF >= 15$$bADV FUNCT MATER : 2022$$d2023-10-24 001021595 920__ $$lyes 001021595 9201_ $$0I:(DE-Juel1)IEK-11-20140314$$kIEK-11$$lHelmholtz-Institut Erlangen-Nürnberg Erneuerbare Energien$$x0 001021595 9801_ $$aFullTexts 001021595 980__ $$ajournal 001021595 980__ $$aVDB 001021595 980__ $$aUNRESTRICTED 001021595 980__ $$aI:(DE-Juel1)IEK-11-20140314 001021595 981__ $$aI:(DE-Juel1)IET-2-20140314