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@PHDTHESIS{Fischer:1022123,
author = {Fischer, Liudmila},
title = {{C}eria-based composites for application in {O}xygen
transport membranes},
volume = {621},
school = {Univ. Twente},
type = {Dissertation},
address = {Jülich},
publisher = {Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag},
reportid = {FZJ-2024-01244},
isbn = {978-3-95806-739-4},
series = {Schriften des Forschungszentrums Jülich Reihe Energie $\&$
Umwelt / Energy $\&$ Environment},
pages = {xiii, 216},
year = {2024},
note = {Dissertation, Univ. Twente, 2024},
abstract = {Among the gas membrane separation technologies, inorganic
dense membranes, like oxygen transport membranes (OTMs), are
regarded as one of the most potential and promising methods
and gain considerable attention over the past decades. OTMs
represent an energy-efficient and economical alternative to
conventional cryogenic air separation for producing pure
oxygen for oxyfuel combustion technologies as they provide
high oxygen selectivity in a single-step process. OTMs
require high permeability as well as chemical and mechanical
stability under harsh ambient conditions, like CO2- or SOx -
containing atmospheres. Mixed ionic-electronic conductors
(MIEC) are applied mostly as materials for OTMs. Compared to
diverse single-phase materials, dual-phase composite
materials, i.e., pure ionic-conductor Ce0.8Gd0.2O2-δ
(CGO20) and electronic-conductor FeCo2O4 (FCO), may
potentially fulfil these requirements completely. The
transport properties of the MIEC system are closely related
to the composition and conducting properties of the
individual phases in the composite, as well as
microstructure features, such as density, porosity, grain
size, and the presence of defects. Therefore, the objective
of this work is to determine the relationship between the
composition as well as the morphology of the permeation
properties in the fluorite-spinel ceramic composite.},
cin = {IEK-1},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {899 - ohne Topic (POF4-899)},
pid = {G:(DE-HGF)POF4-899},
typ = {PUB:(DE-HGF)3 / PUB:(DE-HGF)11},
doi = {10.34734/FZJ-2024-01244},
url = {https://juser.fz-juelich.de/record/1022123},
}