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@ARTICLE{Zhao:1024270,
      author       = {Zhao, Tong and Sobolev, Alexander N. and Martinez de Irujo
                      Labalde, Xabier and Kraft, Marvin A. and Zeier, Wolfgang G.},
      title        = {{O}n the influence of the coherence length on the ionic
                      conductivity in mechanochemically synthesized
                      sodium-conducting halides, ${N}a_{3−x} {I}n_{1− x}
                      {Z}r_{ x} {C}l_{ 6}$},
      journal      = {Journal of materials chemistry / A},
      volume       = {12},
      number       = {12},
      issn         = {2050-7488},
      publisher    = {RSC},
      reportid     = {FZJ-2024-02077},
      pages        = {7015 - 7024},
      year         = {2024},
      abstract     = {The Na+ ionic conductivity of ball milled
                      Na3−xIn1−xZrxCl6 rises with increasing Zr content, while
                      that in the subsequently annealed Na3−xIn1−xZrxCl6
                      compounds reaches a maximum conductivity at an intermediate
                      substitution degree (x = 0.5). To clarify the underlying
                      mechanism causing the differing trends, the local structure
                      and coherence length of the ball milled Na3−xIn1−xZrxCl6
                      solid solutions were investigated by pair distribution
                      function analyses. The structural evolution in the ball
                      milled Na3−xIn1−xZrxCl6 series resembles those found in
                      their annealed counterpart, however, its structural
                      coherence length decreases with higher Zr content. By
                      further investigating the transport properties using
                      impedance spectroscopy, this work uncovers a correlation
                      between the coherence length and the ionic conductivity in
                      ball milled Na3−xIn1−xZrxCl6, in which lower structural
                      coherence leads to higher ionic transport. This work
                      indicates an influence of the microstructure beyond unit
                      cell scale onto macroscopic transport properties in these
                      sodium-conducting halide solid electrolytes.},
      cin          = {IEK-12},
      ddc          = {530},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:001161513500001},
      doi          = {10.1039/D3TA07209F},
      url          = {https://juser.fz-juelich.de/record/1024270},
}