Hauptseite > Publikationsdatenbank > On the influence of the coherence length on the ionic conductivity in mechanochemically synthesized sodium-conducting halides, $Na_{3−x} In_{1− x} Zr_{ x} Cl_{ 6}$ > print

001     1024270
005     20250204113818.0
024 7 _ |a 10.1039/D3TA07209F
|2 doi
024 7 _ |a 2050-7488
|2 ISSN
024 7 _ |a 2050-7496
|2 ISSN
024 7 _ |a 10.34734/FZJ-2024-02077
|2 datacite_doi
024 7 _ |a WOS:001161513500001
|2 WOS
037 _ _ |a FZJ-2024-02077
082 _ _ |a 530
100 1 _ |a Zhao, Tong
|0 P:(DE-HGF)0
|b 0
|e First author
245 _ _ |a On the influence of the coherence length on the ionic conductivity in mechanochemically synthesized sodium-conducting halides, $Na_{3−x} In_{1− x} Zr_{ x} Cl_{ 6}$
260 _ _ |c 2024
|b RSC
336 7 _ |a article
|2 DRIVER
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|b journal
|m journal
|0 PUB:(DE-HGF)16
|s 1711523428_18110
|2 PUB:(DE-HGF)
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a Journal Article
|0 0
|2 EndNote
520 _ _ |a The Na+ ionic conductivity of ball milled Na3−xIn1−xZrxCl6 rises with increasing Zr content, while that in the subsequently annealed Na3−xIn1−xZrxCl6 compounds reaches a maximum conductivity at an intermediate substitution degree (x = 0.5). To clarify the underlying mechanism causing the differing trends, the local structure and coherence length of the ball milled Na3−xIn1−xZrxCl6 solid solutions were investigated by pair distribution function analyses. The structural evolution in the ball milled Na3−xIn1−xZrxCl6 series resembles those found in their annealed counterpart, however, its structural coherence length decreases with higher Zr content. By further investigating the transport properties using impedance spectroscopy, this work uncovers a correlation between the coherence length and the ionic conductivity in ball milled Na3−xIn1−xZrxCl6, in which lower structural coherence leads to higher ionic transport. This work indicates an influence of the microstructure beyond unit cell scale onto macroscopic transport properties in these sodium-conducting halide solid electrolytes.
536 _ _ |a 1221 - Fundamentals and Materials (POF4-122)
|0 G:(DE-HGF)POF4-1221
|c POF4-122
|f POF IV
|x 0
588 _ _ |a Dataset connected to CrossRef, Journals: juser.fz-juelich.de
700 1 _ |a Sobolev, Alexander N.
|b 1
700 1 _ |a Martinez de Irujo Labalde, Xabier
|b 2
700 1 _ |a Kraft, Marvin A.
|0 P:(DE-Juel1)192207
|b 3
700 1 _ |a Zeier, Wolfgang G.
|0 P:(DE-Juel1)184735
|b 4
|e Corresponding author
773 _ _ |a 10.1039/D3TA07209F
|g Vol. 12, no. 12, p. 7015 - 7024
|0 PERI:(DE-600)2702232-8
|n 12
|p 7015 - 7024
|t Journal of materials chemistry / A
|v 12
|y 2024
|x 2050-7488
856 4 _ |y OpenAccess
|u https://juser.fz-juelich.de/record/1024270/files/d3ta07209f.pdf
856 4 _ |y OpenAccess
|x icon
|u https://juser.fz-juelich.de/record/1024270/files/d3ta07209f.gif?subformat=icon
856 4 _ |y OpenAccess
|x icon-1440
|u https://juser.fz-juelich.de/record/1024270/files/d3ta07209f.jpg?subformat=icon-1440
856 4 _ |y OpenAccess
|x icon-180
|u https://juser.fz-juelich.de/record/1024270/files/d3ta07209f.jpg?subformat=icon-180
856 4 _ |y OpenAccess
|x icon-640
|u https://juser.fz-juelich.de/record/1024270/files/d3ta07209f.jpg?subformat=icon-640
909 C O |o oai:juser.fz-juelich.de:1024270
|p openaire
|p open_access
|p VDB
|p driver
|p dnbdelivery
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 3
|6 P:(DE-Juel1)192207
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 4
|6 P:(DE-Juel1)184735
913 1 _ |a DE-HGF
|b Forschungsbereich Energie
|l Materialien und Technologien für die Energiewende (MTET)
|1 G:(DE-HGF)POF4-120
|0 G:(DE-HGF)POF4-122
|3 G:(DE-HGF)POF4
|2 G:(DE-HGF)POF4-100
|4 G:(DE-HGF)POF
|v Elektrochemische Energiespeicherung
|9 G:(DE-HGF)POF4-1221
|x 0
914 1 _ |y 2024
915 _ _ |a Creative Commons Attribution CC BY 3.0
|0 LIC:(DE-HGF)CCBY3
|2 HGFVOC
915 _ _ |a WoS
|0 StatID:(DE-HGF)0113
|2 StatID
|b Science Citation Index Expanded
|d 2023-08-23
915 _ _ |a OpenAccess
|0 StatID:(DE-HGF)0510
|2 StatID
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0160
|2 StatID
|b Essential Science Indicators
|d 2023-08-23
915 _ _ |a National-Konsortium
|0 StatID:(DE-HGF)0430
|2 StatID
|d 2024-12-05
|w ger
915 _ _ |a JCR
|0 StatID:(DE-HGF)0100
|2 StatID
|b J MATER CHEM A : 2022
|d 2024-12-05
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0200
|2 StatID
|b SCOPUS
|d 2024-12-05
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0300
|2 StatID
|b Medline
|d 2024-12-05
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0199
|2 StatID
|b Clarivate Analytics Master Journal List
|d 2024-12-05
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)1150
|2 StatID
|b Current Contents - Physical, Chemical and Earth Sciences
|d 2024-12-05
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)1160
|2 StatID
|b Current Contents - Engineering, Computing and Technology
|d 2024-12-05
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0150
|2 StatID
|b Web of Science Core Collection
|d 2024-12-05
915 _ _ |a IF >= 10
|0 StatID:(DE-HGF)9910
|2 StatID
|b J MATER CHEM A : 2022
|d 2024-12-05
920 1 _ |0 I:(DE-Juel1)IEK-12-20141217
|k IEK-12
|l Helmholtz-Institut Münster Ionenleiter für Energiespeicher
|x 0
980 1 _ |a FullTexts
980 _ _ |a journal
980 _ _ |a VDB
980 _ _ |a UNRESTRICTED
980 _ _ |a I:(DE-Juel1)IEK-12-20141217
981 _ _ |a I:(DE-Juel1)IMD-4-20141217

LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21