TY  - JOUR
AU  - Helm, Bianca
AU  - Strotmann, Kyra
AU  - Böger, Thorben
AU  - Samanta, Bibek
AU  - Banik, Ananya
AU  - Lange, Martin A.
AU  - Li, Yuheng
AU  - Li, Cheng
AU  - Hansen, Michael Ryan
AU  - Canepa, Pieremanuele
AU  - Zeier, Wolfgang G.
TI  - Reducing the Defect Formation Energy by Aliovalent Sn(+IV) and Isovalent P(+V) Substitution in $Li_3SbS_4$ Promotes Li${^+}$ Transport
JO  - ACS applied energy materials
VL  - 7
IS  - 5
SN  - 2574-0962
CY  - Washington, DC
PB  - ACS Publications
M1  - FZJ-2024-02079
SP  - 1735 - 1747
PY  - 2024
AB  - The search for highly conducting Li+ solid electrolytes focuses on sulfide- and halide-based materials, where typically the strongly atomic disordered materials are the most promising. The atomic disorder corresponds to a flattened energy landscape having similar relative site energies for different Li+ positions facilitating motion. In addition, the highly disordered Li+ conductors have negligible defect formation energy as moving charges are readily available. This work investigates the isovalent Li3Sb1–xPxS4 (0 ≤ x ≤ 0.5) and the aliovalent Li3+xSb1–xSnxS4 (0 ≤ x ≤ 0.2) substitution series of thio-LISICON materials by using X-ray diffraction, high-resolution neutron diffraction, impedance spectroscopy, and defect calculations. The starting composition Li3SbS4 has a low ionic conductivity of ∼10–11 S·cm–1 and both substituents improve the ionic conductivity strongly by up to 4 orders of magnitude. On the one hand, in substituted Li3SbS4 structures, only minor structural changes are observed which cannot sufficiently explain the significant impact on the Li+ conductivity. On the other hand, the Li+ carrier density reveals a correlation to the activation energy and first-principles defect calculations, displaying significantly reduced defect formation energy upon substitution. Here, we show within two different substitution series that the defect formation energy plays a major role for ionic motion in this class of thio-LISICON materials.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:001176923300001
DO  - DOI:10.1021/acsaem.3c02652
UR  - https://juser.fz-juelich.de/record/1024272
ER  -