% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Vijayakumar:1024596,
      author       = {Vijayakumar, Vidyanand and Diddens, Diddo and Heuer,
                      Andreas and Kurungot, Sreekumar and Winter, Martin and Nair,
                      Jijeesh Ravi},
      title        = {{D}ioxolanone-{A}nchored {P}oly(allyl ether)-{B}ased
                      {C}ross-{L}inked {D}ual-{S}alt {P}olymer {E}lectrolytes for
                      {H}igh-{V}oltage {L}ithium {M}etal {B}atteries},
      journal      = {ACS applied materials $\&$ interfaces},
      volume       = {12},
      number       = {1},
      issn         = {1944-8244},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2024-02270},
      pages        = {567 - 579},
      year         = {2020},
      abstract     = {Novel cross-linked polymer electrolytes (XPEs) are
                      synthesized by free-radical copolymerization induced by
                      ultraviolet (UV)-light irradiation of a reactive solution,
                      which is composed of a difunctional poly(ethylene glycol)
                      diallyl ether oligomer (PEGDAE), a monofunctional reactive
                      diluent 4-vinyl-1,3-dioxolan-2-one (VEC), and a stock
                      solution containing lithium salt (lithium
                      bis(trifluoromethanesulfonyl)imide, LiTFSI) in a
                      carbonate-free nonvolatile plasticizer, poly(ethylene
                      glycol) dimethyl ether (PEGDME). The resulting polymer
                      matrix can be represented as a linear polyethylene chain
                      functionalized with cyclic carbonate (dioxolanone) moieties
                      and cross-linked by ethylene oxide units. A series of XPEs
                      are prepared by varying the [O]/[Li] ratio (24 to 3) of the
                      stock solution and thoroughly characterized using
                      physicochemical (thermogravimetric analysis–mass
                      spectrometry, differential scanning calorimetry, NMR, etc.)
                      and electrochemical techniques. In addition, quantum
                      chemical calculations are performed to elucidate the
                      correlation between the electrochemical oxidation potential
                      and the lithium ion–ethylene oxide coordination in the
                      stock solution. Later, lithium bis(fluorosulfonyl)imide
                      (LiFSI) salt is incorporated into the electrolyte system to
                      produce a dual-salt XPE that exhibits improved
                      electrochemical performance, a stable interface against
                      lithium metal, and enhanced physical and chemical
                      characteristics to be employed against high-voltage
                      cathodes. The XPE membranes demonstrated excellent
                      resistance against lithium dendrite growth even after
                      reversibly plating and stripping lithium ions for more than
                      1000 h with a total capacity of 0.5 mAh cm–2. Finally, the
                      XPE films are assembled in a lab-scale lithium metal battery
                      configuration by using carbon-coated LiFePO4 (LFP) or
                      LiNi0.8Co0.15Al0.05O2 (NCA) as a cathode and
                      galvanostatically cycled at 20, 40, and 60 °C. Remarkably,
                      at 20 °C, the NCA-based lithium metal cells displayed
                      excellent cycling stability and good capacity retention
                      $(>50\%)$ even after 1000 cycles.},
      cin          = {IEK-12},
      ddc          = {600},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1222 - Components and Cells (POF4-122) / 1223 - Batteries
                      in Application (POF4-122) / FestBatt-Polymere -
                      Materialplattform 'Polymere' im Rahmen des Kompetenzclusters
                      für Festkörperbatterien (13XP0175A)},
      pid          = {G:(DE-HGF)POF4-1222 / G:(DE-HGF)POF4-1223 /
                      G:(BMBF)13XP0175A},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {31825198},
      UT           = {WOS:000507146100052},
      doi          = {10.1021/acsami.9b16348},
      url          = {https://juser.fz-juelich.de/record/1024596},
}