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@ARTICLE{Park:1024674,
author = {Park, Junbeom and Cheng, Ningyan and Ge, Binghui and Jodat,
Eva and Karl, André and Pivak, Yevheniy and Sun, Hongyu and
Garza, Héctor Hugo Pérez and Basak, Shibabrata and Eichel,
Rüdiger-A.},
title = {{T}itanium {N}itride {M}icroelectrode: {A} {N}ew
{C}andidate for {I}n {S}itu {E}lectrochemical {T}ransmission
{E}lectron {M}icroscopy {S}tudy},
journal = {Advanced engineering materials},
volume = {26},
number = {10},
issn = {1438-1656},
address = {Weinheim},
publisher = {Wiley-VCH Verl.},
reportid = {FZJ-2024-02347},
pages = {2302146},
year = {2024},
abstract = {In situ transmission electron microscopy (TEM) is
increasingly utilized by researchers to explore various
electrochemical applications in the quest to address climate
change, aiming to comprehend underlying mechanisms and
enhance performance. However, the conventional Pt
microelectrode commonly used in in situ TEM poses
limitations due to its low electron transparency and high
catalytic activity. In this study, titanium nitride (TiNx)
is introduced as a novel microelectrode material that can be
fabricated following typical cleanroom processes. Through
in situ Zn and Cu electrodeposition studies, it is shown
how the low catalytic activity and higher electron
transparency of TiNx enable obtaining stable electrochemical
cycling and quantify the deposition on top of microelectrode
in TEM mode, highlighting the benefit of TiNx
microelectrodes for different in situ TEM studies.},
cin = {IEK-9},
ddc = {660},
cid = {I:(DE-Juel1)IEK-9-20110218},
pnm = {1232 - Power-based Fuels and Chemicals (POF4-123)},
pid = {G:(DE-HGF)POF4-1232},
typ = {PUB:(DE-HGF)16},
UT = {WOS:001196049700001},
doi = {10.1002/adem.202302146},
url = {https://juser.fz-juelich.de/record/1024674},
}