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@ARTICLE{Klick:1024720,
author = {Klick, Sebastian and Stahl, Gereon and Sauer, Dirk Uwe},
title = {{T}he {I}nfluence of {E}lectrolyte {V}olume on {C}alendaric
{A}ging of {L}ithium‐{I}on {B}atteries},
journal = {Energy technology},
volume = {12},
number = {1},
issn = {2194-4288},
address = {Weinheim [u.a.]},
publisher = {Wiley-VCH},
reportid = {FZJ-2024-02386},
pages = {2300566},
year = {2024},
note = {Gefördert durch zwei weitere BMBF-Projekte - Meet-HiEnD
III (BMBF03XP0258C) $\&$ BatgasMod (BMBF03XP0311B).},
abstract = {Lithium-ion cells with graphite anodes and
nickel–manganese–cobalt oxide (NMC622) cathodes are
filled with three different amounts of electrolyte. During
formation, incremental capacity analysis indicates small
differences in the formation processes between cells with
insufficient electrolytes to fill all pores and those with
an electrolyte volume above the total pore volume of the
cell. Complimentary analysis of the gases developed during
formation shows that the composition of these cells differs
from the cells with a sufficient electrolyte. The aging of
cells under high temperature (60 °C) and high constant
voltage of 4.2 V is studied. During aging, cells with
higher amounts of electrolyte degrade substantially slower.
Based on data available from electrical tests, a theory
explaining the volume-dependent rise of resistance and
capacity decay is proposed.},
cin = {IEK-12},
ddc = {620},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {1223 - Batteries in Application (POF4-122) / BMBF 03XP0349A
- E-FloA - Elektrolyt-Floating-Analyse an
Lithium-Ionen-Zellen mit dem Ziel der Quantifizierung der
Elektrolytdegradation und Deckschichtbildung
(BMBF-03XP0349A)},
pid = {G:(DE-HGF)POF4-1223 / G:(DE-82)BMBF-03XP0349A},
typ = {PUB:(DE-HGF)16},
UT = {WOS:001089056000001},
doi = {10.1002/ente.202300566},
url = {https://juser.fz-juelich.de/record/1024720},
}