guest ::
| Home > Publications database > Functionalized Thiophosphate and Oxidic Filler Particles for Hybrid Solid Electrolytes > print |
| Home > Publications database > Functionalized Thiophosphate and Oxidic Filler Particles for Hybrid Solid Electrolytes > print |
| 001 | 1024752 | ||
| 005 | 20250203103147.0 | ||
| 024 | 7 | _ | |a 10.1002/celc.202300310 |2 doi |
| 024 | 7 | _ | |a 10.34734/FZJ-2024-02418 |2 datacite_doi |
| 024 | 7 | _ | |a WOS:001085756300001 |2 WOS |
| 037 | _ | _ | |a FZJ-2024-02418 |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Helmers, Laura |0 0000-0002-9450-8037 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Functionalized Thiophosphate and Oxidic Filler Particles for Hybrid Solid Electrolytes |
| 260 | _ | _ | |a Weinheim |c 2023 |b Wiley-VCH |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1712723262_14826 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 500 | _ | _ | |a Unterstützt durch: BMBF 3XP0202F (3D-SSB) & BMBF 03XP0432A (FB2-Prod) |
| 520 | _ | _ | |a To achieve the commercialization of solid-state-batteries (SSBs), solid electrolyte properties need to be further improved. The hybrid solid electrolyte (HSE) approach is expected to combine the favorable properties of different solid electrolyte classes and is therefore systematically investigated. Mixing low amounts of thiophosphate or oxide filler particles (FP) into a polyethylene oxide (PEO) polyethylene glycol (PEG) and lithium salt bis(trifluoromethane)sulfonimide (LiTFSI) matrix cannot improve the electrochemical properties. Silanization of the thiophosphate FPs significantly increases the ionic conductivity to 0.1 mS cm−1 at room temperature compared to 0.017 mS cm−1 for a pure PEO solid electrolyte. Moreover, a correlation between the intrinsic conductivity of the FPs and the resulting conductivity of the HSE is observed. Also, the functionalization is successfully transferred to oxide FPs. In addition to an equally significant increase in ionic conductivity, a strong influence of the crystallite size of the FPs on the resulting ionic conductivity of the HSE was found. The discovered effect of FP surface structure on overall HSE conductivity indicates a participation of the FP surface in ion transport and emphasizes the need for tailored filler design in HSE applications. |
| 536 | _ | _ | |a 1221 - Fundamentals and Materials (POF4-122) |0 G:(DE-HGF)POF4-1221 |c POF4-122 |f POF IV |x 0 |
| 588 | _ | _ | |a Dataset connected to CrossRef, Journals: juser.fz-juelich.de |
| 700 | 1 | _ | |a Frankenberg, Finn |0 0009-0005-0644-1565 |b 1 |
| 700 | 1 | _ | |a Brokmann, Julian |b 2 |
| 700 | 1 | _ | |a Burmeister, Christine |0 0000-0003-1128-8735 |b 3 |
| 700 | 1 | _ | |a Buchheit, Annika |0 P:(DE-Juel1)180325 |b 4 |
| 700 | 1 | _ | |a Kwade, Arno |0 0000-0002-6348-7309 |b 5 |
| 700 | 1 | _ | |a Michalowski, Peter |0 0000-0001-6738-8108 |b 6 |
| 773 | _ | _ | |a 10.1002/celc.202300310 |g Vol. 10, no. 21, p. e202300310 |0 PERI:(DE-600)2724978-5 |n 21 |p e202300310 |t ChemElectroChem |v 10 |y 2023 |x 2196-0216 |
| 856 | 4 | _ | |y OpenAccess |u https://juser.fz-juelich.de/record/1024752/files/ChemElectroChem%20-%202023%20-%20Helmers%20-%20Functionalized%20Thiophosphate%20and%20Oxidic%20Filler%20Particles%20for%20Hybrid%20Solid%20Electrolytes.pdf |
| 856 | 4 | _ | |y OpenAccess |x icon |u https://juser.fz-juelich.de/record/1024752/files/ChemElectroChem%20-%202023%20-%20Helmers%20-%20Functionalized%20Thiophosphate%20and%20Oxidic%20Filler%20Particles%20for%20Hybrid%20Solid%20Electrolytes.gif?subformat=icon |
| 856 | 4 | _ | |y OpenAccess |x icon-1440 |u https://juser.fz-juelich.de/record/1024752/files/ChemElectroChem%20-%202023%20-%20Helmers%20-%20Functionalized%20Thiophosphate%20and%20Oxidic%20Filler%20Particles%20for%20Hybrid%20Solid%20Electrolytes.jpg?subformat=icon-1440 |
| 856 | 4 | _ | |y OpenAccess |x icon-180 |u https://juser.fz-juelich.de/record/1024752/files/ChemElectroChem%20-%202023%20-%20Helmers%20-%20Functionalized%20Thiophosphate%20and%20Oxidic%20Filler%20Particles%20for%20Hybrid%20Solid%20Electrolytes.jpg?subformat=icon-180 |
| 856 | 4 | _ | |y OpenAccess |x icon-640 |u https://juser.fz-juelich.de/record/1024752/files/ChemElectroChem%20-%202023%20-%20Helmers%20-%20Functionalized%20Thiophosphate%20and%20Oxidic%20Filler%20Particles%20for%20Hybrid%20Solid%20Electrolytes.jpg?subformat=icon-640 |
| 909 | C | O | |o oai:juser.fz-juelich.de:1024752 |p openaire |p open_access |p VDB |p driver |p dnbdelivery |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 4 |6 P:(DE-Juel1)180325 |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Energie |l Materialien und Technologien für die Energiewende (MTET) |1 G:(DE-HGF)POF4-120 |0 G:(DE-HGF)POF4-122 |3 G:(DE-HGF)POF4 |2 G:(DE-HGF)POF4-100 |4 G:(DE-HGF)POF |v Elektrochemische Energiespeicherung |9 G:(DE-HGF)POF4-1221 |x 0 |
| 914 | 1 | _ | |y 2024 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |d 2023-08-23 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0160 |2 StatID |b Essential Science Indicators |d 2023-08-23 |
| 915 | _ | _ | |a Creative Commons Attribution CC BY 4.0 |0 LIC:(DE-HGF)CCBY4 |2 HGFVOC |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b CHEMELECTROCHEM : 2022 |d 2023-08-23 |
| 915 | _ | _ | |a DEAL Wiley |0 StatID:(DE-HGF)3001 |2 StatID |d 2023-08-23 |w ger |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0500 |2 StatID |b DOAJ |d 2023-05-30T09:22:20Z |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0501 |2 StatID |b DOAJ Seal |d 2023-05-30T09:22:20Z |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0113 |2 StatID |b Science Citation Index Expanded |d 2023-08-23 |
| 915 | _ | _ | |a Fees |0 StatID:(DE-HGF)0700 |2 StatID |d 2023-08-23 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |d 2023-08-23 |
| 915 | _ | _ | |a IF < 5 |0 StatID:(DE-HGF)9900 |2 StatID |d 2023-08-23 |
| 915 | _ | _ | |a OpenAccess |0 StatID:(DE-HGF)0510 |2 StatID |
| 915 | _ | _ | |a Peer Review |0 StatID:(DE-HGF)0030 |2 StatID |b DOAJ : Anonymous peer review |d 2023-05-30T09:22:20Z |
| 915 | _ | _ | |a Article Processing Charges |0 StatID:(DE-HGF)0561 |2 StatID |d 2023-08-23 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |d 2023-08-23 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |d 2023-08-23 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Clarivate Analytics Master Journal List |d 2023-08-23 |
| 920 | 1 | _ | |0 I:(DE-Juel1)IEK-12-20141217 |k IEK-12 |l Helmholtz-Institut Münster Ionenleiter für Energiespeicher |x 0 |
| 980 | 1 | _ | |a FullTexts |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a UNRESTRICTED |
| 980 | _ | _ | |a I:(DE-Juel1)IEK-12-20141217 |
| 981 | _ | _ | |a I:(DE-Juel1)IMD-4-20141217 |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|