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@ARTICLE{Mercurio:10248,
author = {Mercurio, G. and McNellis, E.R. and Martin, I. and Hagen,
S. and Leyssner, F. and Soubatch, S. and Meyer, J. and Wolf,
M. and Tegeder, P. and Tautz, F. S. and Reuter, K.},
title = {{S}tructure and {E}nergetics of {A}zobene on {A}g(111):
{B}enchmarking {S}emiempirical {D}ispersion {C}orrection
{A}pproaches},
journal = {Physical review letters},
volume = {104},
issn = {0031-9007},
address = {College Park, Md.},
publisher = {APS},
reportid = {PreJuSER-10248},
pages = {036102},
year = {2010},
note = {Funding by the DFG through SFB658 and TA244, and computing
time within the DEISA Extreme Computing Initiative, is
acknowledged. We thank J. Zegenhagen, Y. Mi, O. Neucheva,
and S. Mohanty for support.},
abstract = {We employ normal-incidence x-ray standing wave and
temperature programed desorption spectroscopy to derive the
adsorption geometry and energetics of the prototypical
molecular switch azobenzene at Ag(111). This allows us to
assess the accuracy of semiempirical correction schemes as a
computationally efficient means to overcome the deficiency
of semilocal density-functional theory with respect to
long-range van derWaals (vdW) interactions. The obtained
agreement underscores the significant improvement provided
by the account of vdW interactions, with remaining
differences mainly attributed to the neglect of electronic
screening at the metallic surface.},
keywords = {J (WoSType)},
cin = {IBN-3 / JARA-FIT},
ddc = {550},
cid = {I:(DE-Juel1)VDB801 / $I:(DE-82)080009_20140620$},
pnm = {Kondensierte Materie},
pid = {G:(DE-Juel1)FUEK414},
shelfmark = {Physics, Multidisciplinary},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000274003100029},
doi = {10.1103/PhysRevLett.104.036102},
url = {https://juser.fz-juelich.de/record/10248},
}