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@ARTICLE{Wu:1024809,
author = {Wu, Miaomiao and Su, Wenqi and Wang, Xingchao and Liu,
Zhibo and Zhang, Fei and Luo, Zhiqiang and Yang, Aikai and
Yeleken, Palizhaye and Miao, Zezhong and Huang, Yudai},
title = {{L}ong-{L}ife {A}queous {Z}inc–{O}rganic {B}atteries with
a {T}rimethyl {P}hosphate {E}lectrolyte and {O}rganic
{C}athode},
journal = {ACS sustainable chemistry $\&$ engineering},
volume = {11},
number = {3},
issn = {2168-0485},
address = {Washington, DC},
publisher = {ACS Publ.},
reportid = {FZJ-2024-02475},
pages = {957 - 964},
year = {2023},
abstract = {Aqueous zinc batteries (AZBs) are environment-friendly
batteries with good application prospects. However, their
applications are plagued by the dendrite growth of Zn anodes
and the absence of suitable cathodes. Herein, we design and
realize high-performance AZBs by using an organic cathode of
5,7,12,14-pentacenetetrone (PT) and a trimethyl phosphate
(TMP)/water hybrid electrolyte. The COMSOL simulations and
spectroscopy studies collectively demonstrate a strong
interaction between TMP and Zn2+, thus changing the
solvation structure and suppressing the parasitic reactions,
finally enabling dendrite-free Zn plating/stripping. The
hybrid electrolyte shows good compatibility with the PT
cathode. As a consequence, the Zn//PT full cell employing
the hybrid electrolyte exhibits remarkable capacity (229.4
mA h g–1 at 0.1 A g–1), extraordinary rate performance,
and long-term cycling $(84.18\%$ retention after 9600
cycles) at a wide temperature range (−20 to 65 °C).},
cin = {IEK-1},
ddc = {540},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {1222 - Components and Cells (POF4-122)},
pid = {G:(DE-HGF)POF4-1222},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000913267500001},
doi = {10.1021/acssuschemeng.2c05410},
url = {https://juser.fz-juelich.de/record/1024809},
}