Home > Publications database > Long-Life Aqueous Zinc–Organic Batteries with a Trimethyl Phosphate Electrolyte and Organic Cathode > print |
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024 | 7 | _ | |a 10.1021/acssuschemeng.2c05410 |2 doi |
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100 | 1 | _ | |a Wu, Miaomiao |0 P:(DE-HGF)0 |b 0 |
245 | _ | _ | |a Long-Life Aqueous Zinc–Organic Batteries with a Trimethyl Phosphate Electrolyte and Organic Cathode |
260 | _ | _ | |a Washington, DC |c 2023 |b ACS Publ. |
336 | 7 | _ | |a article |2 DRIVER |
336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1721825053_8782 |2 PUB:(DE-HGF) |
336 | 7 | _ | |a ARTICLE |2 BibTeX |
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336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
520 | _ | _ | |a Aqueous zinc batteries (AZBs) are environment-friendly batteries with good application prospects. However, their applications are plagued by the dendrite growth of Zn anodes and the absence of suitable cathodes. Herein, we design and realize high-performance AZBs by using an organic cathode of 5,7,12,14-pentacenetetrone (PT) and a trimethyl phosphate (TMP)/water hybrid electrolyte. The COMSOL simulations and spectroscopy studies collectively demonstrate a strong interaction between TMP and Zn2+, thus changing the solvation structure and suppressing the parasitic reactions, finally enabling dendrite-free Zn plating/stripping. The hybrid electrolyte shows good compatibility with the PT cathode. As a consequence, the Zn//PT full cell employing the hybrid electrolyte exhibits remarkable capacity (229.4 mA h g–1 at 0.1 A g–1), extraordinary rate performance, and long-term cycling (84.18% retention after 9600 cycles) at a wide temperature range (−20 to 65 °C). |
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588 | _ | _ | |a Dataset connected to CrossRef, Journals: juser.fz-juelich.de |
700 | 1 | _ | |a Su, Wenqi |0 P:(DE-HGF)0 |b 1 |
700 | 1 | _ | |a Wang, Xingchao |0 P:(DE-HGF)0 |b 2 |e Corresponding author |
700 | 1 | _ | |a Liu, Zhibo |0 P:(DE-HGF)0 |b 3 |
700 | 1 | _ | |a Zhang, Fei |0 P:(DE-HGF)0 |b 4 |
700 | 1 | _ | |a Luo, Zhiqiang |0 P:(DE-HGF)0 |b 5 |
700 | 1 | _ | |a Yang, Aikai |0 P:(DE-Juel1)180575 |b 6 |u fzj |
700 | 1 | _ | |a Yeleken, Palizhaye |0 P:(DE-HGF)0 |b 7 |
700 | 1 | _ | |a Miao, Zezhong |0 P:(DE-HGF)0 |b 8 |
700 | 1 | _ | |a Huang, Yudai |0 P:(DE-HGF)0 |b 9 |
773 | _ | _ | |a 10.1021/acssuschemeng.2c05410 |g Vol. 11, no. 3, p. 957 - 964 |0 PERI:(DE-600)2695697-4 |n 3 |p 957 - 964 |t ACS sustainable chemistry & engineering |v 11 |y 2023 |x 2168-0485 |
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