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@ARTICLE{Liu:1024810,
author = {Liu, Xianyu and Lu, Qiongqiong and Yang, Aikai and Qian,
Yitai},
title = {{H}igh ionic conductive protection layer on {Z}n metal
anode for enhanced aqueous zinc-ion batteries},
journal = {Chinese chemical letters},
volume = {34},
number = {6},
issn = {1001-8417},
address = {London},
publisher = {Elsevier},
reportid = {FZJ-2024-02476},
pages = {107703 -},
year = {2023},
abstract = {Aqueous zinc-ion batteries (ZIBs) has been regarded as a
promising energy storage system for large-scale application
due to the advantages of low cost and high safety. However,
the growth of Zn dendrite, hydrogen evolution and
passivation issues induce the poor electrochemical
performance of ZIBs. Herein, a Na3Zr2Si2PO12 (NZSP)
protection layer with high ionic conductivity of 2.94 mS/cm
on Zn metal anode was fabricated by drop casting approach.
The protection layer prevents Zn dendrites formation,
hydrogen evolution as well as passivation, and facilitates a
fast Zn2+ transport. As a result, the symmetric cells based
on NZSP-coated Zn show a stable cycling over 1360 h at
0.5 mA/cm2 with 0.5 mAh/cm2 and 1000 h even at a high
current density of 5 mA/cm2 with 2 mAh/cm2. Moreover, the
full cells combined with V2O5-based cathode displays high
capacities and high rate capability. This work offers a
facile and effective approach to stabilizing Zn metal anode
for enhanced ZIBs.},
cin = {IEK-1},
ddc = {540},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {1213 - Cell Design and Development (POF4-121) / 1222 -
Components and Cells (POF4-122)},
pid = {G:(DE-HGF)POF4-1213 / G:(DE-HGF)POF4-1222},
typ = {PUB:(DE-HGF)16},
UT = {WOS:001008046600001},
doi = {10.1016/j.cclet.2022.07.046},
url = {https://juser.fz-juelich.de/record/1024810},
}