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@ARTICLE{Wang:1024812,
author = {Wang, Pengyue and Hu, Tianran and Guo, Yong and Cui,
Yincang and Wang, Ruiying and Yang, Aikai and Huang, Yudai
and Wang, Xingchao},
title = {{C}o{S}2 confined into {N}-doped coal-based carbon fiber as
flexible anode for high performance potassium-ion capacitor},
journal = {Journal of alloys and compounds},
volume = {970},
issn = {0925-8388},
address = {Lausanne},
publisher = {Elsevier},
reportid = {FZJ-2024-02478},
pages = {172618 -},
year = {2024},
abstract = {Potassium-ion capacitors (PICs), skillfully combining the
features of batteries and capacitors, hold promise in energy
conversion and storage. Cobalt sulfide (CoS2) anode are
promising alternatives due to its high theoretical capacity
and excellent potassium storage capacity. However, severe
volume changes of CoS2 anode leads to capacity decline and
poor cycle stability, hindering its application in PICs.
Herein, we successfully confine CoS2 nanoparticles in
N-doped coal-based carbon fibers (CoS2/CF). Coal-based
carbon fibers with flexible characteristic elevate the
conductivity and relieve the volume expansion of CoS2.
Moreover, the high content of edge nitrogen as active sites
further enhances the electrochemical properties. The PICs
with flexible CoS2/CF-0.8 as anode exhibits superior
specific capacity (331.1 mA h g−1 after 150 cycles at 0.1
A g−1) and long cycling (214.1 mA h g−1 after 900 cycles
at 1.0 A g−1). Ex-situ X-ray powder diffraction (XRD)
reveal that the mechanism of CoS2/CF-0.8 anode is based on
reversible intercalation and conversion reaction.
Importantly, CoS2/CF-0.8||activated carbon (AC) devices
shows excellent energy density (101.9 W h kg−1) and long
cycling $(82.23\%$ capacity maintenance rate after 1000
cycles). This work offers insights for other materials with
high theoretical capacity but volume expansion problem.},
cin = {IEK-1},
ddc = {540},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {1221 - Fundamentals and Materials (POF4-122)},
pid = {G:(DE-HGF)POF4-1221},
typ = {PUB:(DE-HGF)16},
UT = {WOS:001101300000002},
doi = {10.1016/j.jallcom.2023.172618},
url = {https://juser.fz-juelich.de/record/1024812},
}