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@ARTICLE{Lv:1024841,
author = {Lv, Hua and da Silva, Alessandra and Figueroa, Adriana I.
and Guillemard, Charles and Aguirre, Iván Fernández and
Camosi, Lorenzo and Aballe, Lucia and Valvidares, Manuel and
Valenzuela, Sergio O. and Schubert, Jürgen and Schmidbauer,
Martin and Herfort, Jens and Hanke, Michael and Trampert,
Achim and Engel-Herbert, Roman and Ramsteiner, Manfred and
Lopes, Joao Marcelo J.},
title = {{L}arge‐{A}rea {S}ynthesis of {F}erromagnetic {F}e 5− x
{G}e{T}e 2 /{G}raphene van der {W}aals {H}eterostructures
with {C}urie {T}emperature above {R}oom {T}emperature},
journal = {Small},
volume = {19},
number = {39},
issn = {1613-6810},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2024-02507},
pages = {2302387},
year = {2023},
abstract = {Van der Waals (vdW) heterostructures combining layered
ferromagnets and other 2D crystals are promising building
blocks for the realization of ultracompact devices with
integrated magnetic, electronic, and optical
functionalities. Their implementation in various
technologies depends strongly on the development of a
bottom-up scalable synthesis approach allowing for realizing
highly uniform heterostructures with well-defined interfaces
between different 2D-layered materials. It is also required
that each material component of the heterostructure remains
functional, which ideally includes ferromagnetic order above
room temperature for 2D ferromagnets. Here, it is
demonstrated that the large-area growth of
Fe5−xGeTe2/graphene heterostructures is achieved by vdW
epitaxy of Fe5−xGeTe2 on epitaxial graphene. Structural
characterization confirms the realization of a continuous
vdW heterostructure film with a sharp interface between
Fe5−xGeTe2 and graphene. Magnetic and transport studies
reveal that the ferromagnetic order persists well above 300
K with a perpendicular magnetic anisotropy. In addition,
epitaxial graphene on SiC(0001) continues to exhibit a high
electronic quality. These results represent an important
advance beyond nonscalable flake exfoliation and stacking
methods, thus marking a crucial step toward the
implementation of ferromagnetic 2D materials in practical
applications.},
cin = {INM-7 / PGI-9},
ddc = {620},
cid = {I:(DE-Juel1)INM-7-20090406 / I:(DE-Juel1)PGI-9-20110106},
pnm = {5254 - Neuroscientific Data Analytics and AI (POF4-525)},
pid = {G:(DE-HGF)POF4-5254},
typ = {PUB:(DE-HGF)16},
pubmed = {37231567},
UT = {WOS:000994675900001},
doi = {10.1002/smll.202302387},
url = {https://juser.fz-juelich.de/record/1024841},
}