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@ARTICLE{Stuckenberg:1024896,
      author       = {Stuckenberg, Silvan and Bela, Marlena Maria and
                      Lechtenfeld, Christian-Timo and Mense, Maximilian and
                      Küpers, Verena and Ingber, Tjark Thorben Klaus and Winter,
                      Martin and Stan, Marian Cristian},
      title        = {{I}nfluence of {L}i{NO} 3 on the {L}ithium {M}etal
                      {D}eposition {B}ehavior in {C}arbonate‐{B}ased {L}iquid
                      {E}lectrolytes and on the {E}lectrochemical {P}erformance in
                      {Z}ero‐{E}xcess {L}ithium {M}etal {B}atteries},
      journal      = {Small},
      volume       = {20},
      number       = {6},
      issn         = {1613-6810},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2024-02547},
      pages        = {2305203},
      year         = {2024},
      note         = {Unterstützt durch BMBF Grant: ProLiFest (03XP0253A)},
      abstract     = {Continuous lithium (Li) depletion shadows the increase in
                      energy density and safety properties promised by zero-excess
                      lithium metal batteries (ZELMBs). Guiding the Li deposits
                      toward more homogeneous and denser lithium morphology
                      results in improved electrochemical performance. Herein, a
                      lithium nitrate (LiNO3) enriched separator that improves the
                      morphology of the Li deposits and facilitates the formation
                      of an inorganic-rich solid–electrolyte interphase (SEI)
                      resulting in an extended cycle life in Li||Li-cells as well
                      as an increase of the Coulombic efficiency in Cu||Li-cells
                      is reported. Using a LiNi0.6Co0.2Mn0.2O2 positive electrode
                      in NCM622||Cu-cells, a carbonate-based electrolyte, and a
                      LiNO3 enriched separator, an extension of the cycle life by
                      more than 50 cycles with a moderate capacity fading compared
                      to the unmodified separator is obtained. The relative
                      constant level of LiNO3 in the electrolyte, maintained by
                      the LiNO3 enriched separator throughout the cycling process
                      stems at the origin of the improved performance. Ion
                      chromatography measurements carried out at different cycles
                      support the proposed mechanism of a slow and constant
                      release of LiNO3 from the separator. The results indicate
                      that the strategy of using a LiNO3 enriched separator
                      instead of LiNO3 as a sacrificial electrolyte additive can
                      improve the performance of ZELMBs further by maintaining a
                      compact and thus stable SEI layer on Li deposits.},
      cin          = {IEK-12},
      ddc          = {620},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122) / MEET HiEnD
                      III - Materials and Components to Meet High Energy Density
                      Batteries (13XP0258B) / DFG project 509322222 - Struktur,
                      Dynamik und elektrochemische Stabilität von konzentrierten
                      Elektrolyten in begrenzten Umgebungen (509322222)},
      pid          = {G:(DE-HGF)POF4-1221 / G:(BMBF)13XP0258B /
                      G:(GEPRIS)509322222},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {37797185},
      UT           = {WOS:001080896600001},
      doi          = {10.1002/smll.202305203},
      url          = {https://juser.fz-juelich.de/record/1024896},
}