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@ARTICLE{Refino:1024926,
      author       = {Refino, Andam Deatama and Adhitama, Egy and Bela, Marlena
                      M. and Sadhujan, Sumesh and Harilal, Sherina and Eldona,
                      Calvin and Bremers, Heiko and Bashouti, Muhammad Y. and
                      Sumboja, Afriyanti and Stan, Marian C. and Winter, Martin
                      and Placke, Tobias and Peiner, Erwin and Wasisto, Hutomo
                      Suryo},
      title        = {{I}mpact of exposing lithium metal to monocrystalline
                      vertical silicon nanowires for lithium-ion microbatteries},
      journal      = {Communications materials},
      volume       = {4},
      number       = {1},
      issn         = {2662-4443},
      address      = {London},
      publisher    = {Springer Nature},
      reportid     = {FZJ-2024-02576},
      pages        = {58},
      year         = {2023},
      note         = {Zudem unterstützt durch BMBF Projekt: ProLiFest
                      (03XP0253A)},
      abstract     = {Silicon has attracted considerable attention for use as
                      high-capacity anodes of lithium-ion microbatteries. However,
                      its extreme volume change upon (de-)lithiation still poses a
                      challenge for adoption as it leads to severe active lithium
                      loss that shortens the cycle life. Here, we fabricate
                      three-dimensional monocrystalline vertical silicon nanowires
                      on a silicon wafer using low-cost metal-assisted chemical
                      etching, then cover them with lithium using thermal
                      evaporation prior to the battery operation as the
                      pre-lithiation step, to investigate its impact on
                      electrochemical performance. To reveal the underlying
                      physical and electrochemical mechanisms, we also process a
                      comparative planar monocrystalline silicon. We find that
                      pre-lithiation results in improved (de-)lithiation behavior,
                      especially in planar silicon-based cells, while silicon
                      nanowire-based cells exhibit low capacity in early cycles.
                      This study sheds light on the surface design and structural
                      modification of monocrystalline silicon nanowires with
                      respect to pre-lithiation by lithium thermal evaporation.},
      cin          = {IEK-12},
      ddc          = {600},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122) / BACCARA -
                      Battery and superCapacitor ChARActerization and testing
                      (608491)},
      pid          = {G:(DE-HGF)POF4-1221 / G:(EU-Grant)608491},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:001042523700001},
      doi          = {10.1038/s43246-023-00385-0},
      url          = {https://juser.fz-juelich.de/record/1024926},
}