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@ARTICLE{Herbers:1024927,
      author       = {Herbers, Lukas and Küpers, Verena and Winter, Martin and
                      Bieker, Peter},
      title        = {{A}n ionic liquid- and {PEO}-based ternary polymer
                      electrolyte for lithium metal batteries: an advanced
                      processing solvent-free approach for solid electrolyte
                      processing},
      journal      = {RSC Advances},
      volume       = {13},
      number       = {26},
      issn         = {2046-2069},
      address      = {London},
      publisher    = {RSC Publishing},
      reportid     = {FZJ-2024-02577},
      pages        = {17947 - 17958},
      year         = {2023},
      abstract     = {A processing solvent-free manufacturing process for
                      cross-linked ternary solid polymer electrolytes (TSPEs) is
                      presented. Ternary electrolytes (PEODA, Pyr14TFSI, LiTFSI)
                      with high ionic conductivities of >1 mS cm−1 are obtained.
                      It is shown that an increased LiTFSI content in the
                      formulation (10 $wt\%$ to 30 $wt\%)$ decreases the risk of
                      short-circuits by HSAL significantly. The practical areal
                      capacity increases by more than a factor of 20 from 0.42 mA
                      h cm−2 to 8.80 mA h cm−2 before a short-circuit occurs.
                      With increasing Pyr14TFSI content, the temperature
                      dependency of the ionic conductivity changes from
                      Vogel–Fulcher–Tammann to Arrhenius behavior, leading to
                      activation energies for the ion conduction of 0.23 eV. In
                      addition, high Coulombic efficiencies of $93\%$ in Cu‖Li
                      cells and limiting current densities of 0.46 mA cm−2 in
                      Li‖Li cells were obtained. Due to a temperature stability
                      of >300 °C the electrolyte guarantees high safety in a
                      broad window of conditions. In LFP‖Li cells, a high
                      discharge capacity of 150 mA h g−1 after 100 cycles at 60
                      °C was achieved.},
      cin          = {IEK-12},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122) / BACCARA -
                      Battery and superCapacitor ChARActerization and testing
                      (608491)},
      pid          = {G:(DE-HGF)POF4-1221 / G:(EU-Grant)608491},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {37323458},
      UT           = {WOS:001006393700001},
      doi          = {10.1039/D3RA02488A},
      url          = {https://juser.fz-juelich.de/record/1024927},
}