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001024929 1001_ $$aGoodwin, Laura E.$$b0
001024929 245__ $$aHalide and Sulfide Electrolytes in Cathode Composites for Sodium All-Solid-State Batteries and their Stability
001024929 260__ $$aWashington, DC$$bSoc.$$c2024
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001024929 520__ $$aSodium all-solid-state batteries may become a novel storage technology overcoming the safety and energy density issues of (liquid-based) sodium ion batteries at low cost and good resource availability. However, compared to liquid electrolyte cells, contact issues and capacity losses due to interface reactions leading to high cell resistance are still a problem in solid-state batteries. In particular, sulfide-based electrolytes, which show very high ionic conductivity and good malleability, exhibit degradation reactions at the interface with electrode materials and carbon additives. A new group of solid electrolytes, i.e., sodium halides, shows wider potential windows and better stability at typical cathode potentials. A detailed investigation of the interface reactions of Na3SbS4 and Na2.4Er0.4Zr0.6Cl6 as catholytes in cathodes and their cycling performance in full cells is performed. X-ray spectroscopy, time-of-flight spectrometry, and impedance spectroscopy are used to study the interface of each catholyte with a transition metal oxide cathode active material. In addition, impedance measurements were used to study the separator electrolyte Na3SbS4 with the catholyte Na2.4Er0.4Zr0.6Cl6. In conclusion, cathodes with Na2.4Er0.4Zr0.6Cl6 show a higher stability at low C-rates, resulting in lower interfacial resistance and improved cycling performance.
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001024929 536__ $$0G:(BMBF)13XP0187B$$aNASEBER - Natriumbasierte feste Sulfid- und Oxid-Elektrolyt Batterien (13XP0187B)$$c13XP0187B$$x1
001024929 536__ $$0G:(GEPRIS)390874152$$aDFG project 390874152 - EXC 2154: POLiS - Post Lithium Storage Cluster of Excellence (390874152)$$c390874152$$x2
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001024929 7001_ $$aZiegler, Maya$$b1
001024929 7001_ $$aTill, Paul$$b2
001024929 7001_ $$aNazer, Nazia$$b3
001024929 7001_ $$00000-0003-2439-8802$$aAdelhelm, Philipp$$b4
001024929 7001_ $$0P:(DE-Juel1)184735$$aZeier, Wolfgang G.$$b5
001024929 7001_ $$00000-0002-6587-7757$$aRichter, Felix H.$$b6
001024929 7001_ $$00000-0002-9221-4756$$aJanek, Jürgen$$b7
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