% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Goodwin:1024929,
      author       = {Goodwin, Laura E. and Ziegler, Maya and Till, Paul and
                      Nazer, Nazia and Adelhelm, Philipp and Zeier, Wolfgang G.
                      and Richter, Felix H. and Janek, Jürgen},
      title        = {{H}alide and {S}ulfide {E}lectrolytes in {C}athode
                      {C}omposites for {S}odium {A}ll-{S}olid-{S}tate {B}atteries
                      and their {S}tability},
      journal      = {ACS applied materials $\&$ interfaces},
      volume       = {X},
      issn         = {1944-8244},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2024-02579},
      pages        = {acsami.4c01652},
      year         = {2024},
      abstract     = {Sodium all-solid-state batteries may become a novel storage
                      technology overcoming the safety and energy density issues
                      of (liquid-based) sodium ion batteries at low cost and good
                      resource availability. However, compared to liquid
                      electrolyte cells, contact issues and capacity losses due to
                      interface reactions leading to high cell resistance are
                      still a problem in solid-state batteries. In particular,
                      sulfide-based electrolytes, which show very high ionic
                      conductivity and good malleability, exhibit degradation
                      reactions at the interface with electrode materials and
                      carbon additives. A new group of solid electrolytes, i.e.,
                      sodium halides, shows wider potential windows and better
                      stability at typical cathode potentials. A detailed
                      investigation of the interface reactions of Na3SbS4 and
                      Na2.4Er0.4Zr0.6Cl6 as catholytes in cathodes and their
                      cycling performance in full cells is performed. X-ray
                      spectroscopy, time-of-flight spectrometry, and impedance
                      spectroscopy are used to study the interface of each
                      catholyte with a transition metal oxide cathode active
                      material. In addition, impedance measurements were used to
                      study the separator electrolyte Na3SbS4 with the catholyte
                      Na2.4Er0.4Zr0.6Cl6. In conclusion, cathodes with
                      Na2.4Er0.4Zr0.6Cl6 show a higher stability at low C-rates,
                      resulting in lower interfacial resistance and improved
                      cycling performance.},
      cin          = {IEK-12},
      ddc          = {600},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122) / NASEBER -
                      Natriumbasierte feste Sulfid- und Oxid-Elektrolyt Batterien
                      (13XP0187B) / DFG project 390874152 - EXC 2154: POLiS - Post
                      Lithium Storage Cluster of Excellence (390874152)},
      pid          = {G:(DE-HGF)POF4-1221 / G:(BMBF)13XP0187B /
                      G:(GEPRIS)390874152},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {38572658},
      UT           = {WOS:001197397300001},
      doi          = {10.1021/acsami.4c01652},
      url          = {https://juser.fz-juelich.de/record/1024929},
}