001024932 001__ 1024932
001024932 005__ 20250203103405.0
001024932 0247_ $$2doi$$a10.1002/adfm.202210512
001024932 0247_ $$2ISSN$$a1616-301X
001024932 0247_ $$2ISSN$$a1057-9257
001024932 0247_ $$2ISSN$$a1099-0712
001024932 0247_ $$2ISSN$$a1616-3028
001024932 0247_ $$2datacite_doi$$a10.34734/FZJ-2024-02582
001024932 0247_ $$2WOS$$aWOS:000918277100001
001024932 037__ $$aFZJ-2024-02582
001024932 082__ $$a530
001024932 1001_ $$00000-0003-1319-2577$$aTengen, Bärbel$$b0
001024932 245__ $$aImmobilizing Poly(vinylphenothiazine) in Ketjenblack‐Based Electrodes to Access its Full Specific Capacity as Battery Electrode Material
001024932 260__ $$aWeinheim$$bWiley-VCH$$c2023
001024932 3367_ $$2DRIVER$$aarticle
001024932 3367_ $$2DataCite$$aOutput Types/Journal article
001024932 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1712752109_24399
001024932 3367_ $$2BibTeX$$aARTICLE
001024932 3367_ $$2ORCID$$aJOURNAL_ARTICLE
001024932 3367_ $$00$$2EndNote$$aJournal Article
001024932 500__ $$aZudem unterstützt durch: MEET  Hi-EnD  III  (03XP0258A), DFG Germany’s Excellence Strategy (EXC-2193/1- 390951807, grantee A.F.)
001024932 520__ $$aOrganic batteries are considered as environmentally friendly alternative to lithium-ion batteries due to the application of transition metal-free redox-active polymers. One well-established polymer is poly(3-vinyl-N-methylphenothiazine) (PVMPT) with a fast reversibility of the electrochemical redox reaction at a potential of 3.5 V versus Li|Li+. The oxidized PVMPT is soluble in many standard battery electrolytes, which diminishes its available specific capacity but at the same time can lead to a unique charge/discharge mechanism involving a redeposition process upon discharge. Herein, the influence of different conductive carbon additives and their properties, e.g., specific surface area, pore size distribution, and electrical conductivity, on the dissolution behavior of oxidized PVMPT is investigated. Compared to the state-of-the-art conductive carbon Super C65 employed in many organic battery electrodes, Ketjenblack EC-300J and EC-600J reduce the dissolution of the oxidized PVMPT due to better immobilization on the carbon additive and in the resulting 3D structure of the electrode, as assessed by N2-physisorption, electrochemical, UV–vis spectroscopy and scanning electron microscopy investigations. The studies demonstrate that a dense packing of the carbon particles in the electrode is decisive for the stable immobilization of PVMPT while maintaining its long-term cycling performance.
001024932 536__ $$0G:(DE-HGF)POF4-1221$$a1221 - Fundamentals and Materials (POF4-122)$$cPOF4-122$$fPOF IV$$x0
001024932 536__ $$0G:(GEPRIS)398214985$$aDFG project 398214985 - Heteroaromatische Redoxpolymere für Lithium-/organische Batterien (HALO) (398214985)$$c398214985$$x1
001024932 588__ $$aDataset connected to DataCite
001024932 7001_ $$0P:(DE-HGF)0$$aWinkelmann, Timo$$b1
001024932 7001_ $$0P:(DE-HGF)0$$aOrtlieb, Niklas$$b2
001024932 7001_ $$aPerner, Verena$$b3
001024932 7001_ $$aStuder, Gauthier$$b4
001024932 7001_ $$0P:(DE-Juel1)166130$$aWinter, Martin$$b5$$ufzj
001024932 7001_ $$00000-0002-2430-1380$$aEsser, Birgit$$b6
001024932 7001_ $$aFischer, Anna$$b7
001024932 7001_ $$0P:(DE-Juel1)180777$$aBieker, Peter$$b8$$eCorresponding author
001024932 773__ $$0PERI:(DE-600)2039420-2$$a10.1002/adfm.202210512$$gVol. 33, no. 9, p. 2210512$$n9$$p2210512$$tAdvanced functional materials$$v33$$x1616-301X$$y2023
001024932 8564_ $$uhttps://juser.fz-juelich.de/record/1024932/files/Adv%20Funct%20Materials%20-%202023%20-%20Tengen%20-%20Immobilizing%20Poly%20vinylphenothiazine%20in%20Ketjenblack%E2%80%90Based%20Electrodes%20to%20Access%20its.pdf$$yOpenAccess
001024932 8564_ $$uhttps://juser.fz-juelich.de/record/1024932/files/Adv%20Funct%20Materials%20-%202023%20-%20Tengen%20-%20Immobilizing%20Poly%20vinylphenothiazine%20in%20Ketjenblack%E2%80%90Based%20Electrodes%20to%20Access%20its.gif?subformat=icon$$xicon$$yOpenAccess
001024932 8564_ $$uhttps://juser.fz-juelich.de/record/1024932/files/Adv%20Funct%20Materials%20-%202023%20-%20Tengen%20-%20Immobilizing%20Poly%20vinylphenothiazine%20in%20Ketjenblack%E2%80%90Based%20Electrodes%20to%20Access%20its.jpg?subformat=icon-1440$$xicon-1440$$yOpenAccess
001024932 8564_ $$uhttps://juser.fz-juelich.de/record/1024932/files/Adv%20Funct%20Materials%20-%202023%20-%20Tengen%20-%20Immobilizing%20Poly%20vinylphenothiazine%20in%20Ketjenblack%E2%80%90Based%20Electrodes%20to%20Access%20its.jpg?subformat=icon-180$$xicon-180$$yOpenAccess
001024932 8564_ $$uhttps://juser.fz-juelich.de/record/1024932/files/Adv%20Funct%20Materials%20-%202023%20-%20Tengen%20-%20Immobilizing%20Poly%20vinylphenothiazine%20in%20Ketjenblack%E2%80%90Based%20Electrodes%20to%20Access%20its.jpg?subformat=icon-640$$xicon-640$$yOpenAccess
001024932 909CO $$ooai:juser.fz-juelich.de:1024932$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
001024932 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)166130$$aForschungszentrum Jülich$$b5$$kFZJ
001024932 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)180777$$aForschungszentrum Jülich$$b8$$kFZJ
001024932 9131_ $$0G:(DE-HGF)POF4-122$$1G:(DE-HGF)POF4-120$$2G:(DE-HGF)POF4-100$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF4-1221$$aDE-HGF$$bForschungsbereich Energie$$lMaterialien und Technologien für die Energiewende (MTET)$$vElektrochemische Energiespeicherung$$x0
001024932 9141_ $$y2024
001024932 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2023-10-24
001024932 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2023-10-24
001024932 915__ $$0StatID:(DE-HGF)1230$$2StatID$$aDBCoverage$$bCurrent Contents - Electronics and Telecommunications Collection$$d2023-10-24
001024932 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
001024932 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search$$d2023-10-24
001024932 915__ $$0StatID:(DE-HGF)9915$$2StatID$$aIF >= 15$$bADV FUNCT MATER : 2022$$d2023-10-24
001024932 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2023-10-24
001024932 915__ $$0StatID:(DE-HGF)3001$$2StatID$$aDEAL Wiley$$d2023-10-24$$wger
001024932 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2023-10-24
001024932 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2023-10-24
001024932 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
001024932 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC$$d2023-10-24
001024932 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bADV FUNCT MATER : 2022$$d2023-10-24
001024932 915__ $$0StatID:(DE-HGF)1160$$2StatID$$aDBCoverage$$bCurrent Contents - Engineering, Computing and Technology$$d2023-10-24
001024932 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2023-10-24
001024932 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2023-10-24
001024932 9201_ $$0I:(DE-Juel1)IEK-12-20141217$$kIEK-12$$lHelmholtz-Institut Münster Ionenleiter für Energiespeicher$$x0
001024932 9801_ $$aFullTexts
001024932 980__ $$ajournal
001024932 980__ $$aVDB
001024932 980__ $$aUNRESTRICTED
001024932 980__ $$aI:(DE-Juel1)IEK-12-20141217
001024932 981__ $$aI:(DE-Juel1)IMD-4-20141217