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@ARTICLE{Stolz:1024999,
      author       = {Stolz, Lukas and Winter, Martin and Kasnatscheew, Johannes},
      title        = {{P}ractical relevance of charge transfer resistance at the
                      {L}i metal electrode|electrolyte interface in batteries?},
      journal      = {Journal of solid state electrochemistry},
      volume       = {29},
      issn         = {1432-8488},
      address      = {New York},
      publisher    = {Springer},
      reportid     = {FZJ-2024-02593},
      pages        = {4181-4186},
      year         = {2025},
      note         = {Unterstützt durch BMBF Grants: MEET Hi-End III (03XP0258A)
                      und als Teil des ExcellBattMat Clusters.},
      abstract     = {The theoretically possible energy and power densities of
                      rechargeable batteries are practically limited by
                      resistances as these lead to overvoltages, particularly
                      pronounced at kinetically harsher conditions, i.e., high
                      currents and/or low temperature. Charge transfer resistance
                      (Rct), being a major type of resistance alongside with Ohmic
                      (RΩ) and mass transport (Rmt), is related with the
                      activation hindrance of electrochemical reactions. Its
                      practical relevance is discussed within this work via
                      analyzing cells with the galvanostatic/constant current (CC)
                      technique. Rct at Li|electrolyte interfaces is shown to be
                      relevantly impacted by electrode–electrolyte interphases;
                      implying the electrolyte type, as well. While solid polymer
                      electrolytes (SPEs), e.g., based on poly(ethylene) oxide
                      (PEO), show negligible Rct, it is evident for commercial
                      liquid electrolytes and readily increase during storage.
                      Given the asymptotic overvoltage vs. current behavior of
                      Rct, obeying Butler-Volmer equation, Rct gets less relevant
                      at enhanced currents, as experimentally validated, finally
                      pointing to the dominance of RΩ and (depending on system)
                      Rmt in the overall resistance.},
      cin          = {IEK-12},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:001140428000001},
      doi          = {10.1007/s10008-023-05792-4},
      url          = {https://juser.fz-juelich.de/record/1024999},
}