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@ARTICLE{Tomar:1025004,
      author       = {Tomar, Anubha and Vankani, Chirag and Singh, Satendra Pal
                      and Winter, Martin and Rai, Alok Kumar},
      title        = {{B}oosting the high-rate performance of lithium-ion battery
                      anodes using {M}n{C}o 2 {O} 4 /{C}o 3 {O} 4 nanocomposite
                      interfaces},
      journal      = {Physical chemistry, chemical physics},
      volume       = {26},
      number       = {4},
      issn         = {1463-9076},
      address      = {Cambridge},
      publisher    = {RSC Publ.},
      reportid     = {FZJ-2024-02598},
      pages        = {3516 - 3524},
      year         = {2024},
      abstract     = {Herein, a mesoporous MnCo2O4/Co3O4 nanocomposite was
                      fabricated using a polyvinylpyrrolidone (PVP)-assisted
                      hydrothermal synthesis method by maintaining only the
                      non-stoichiometric ratio of Mn and Co (2 : 6), leading
                      to an extra phase of Co3O4 coupled with MnCo2O4.
                      Microstructural analysis showed that the obtained sample has
                      a uniform nanowire-like morphology composed of
                      interconnected nanoparticles. The stoichiometric ratio
                      (2 : 4) was maintained to synthesize pure MnCo2O4 for
                      comparative analysis. However, the obtained structure of
                      pure MnCo2O4 was found to be irregular and fragile. After
                      their employment as anode-active materials, the
                      nanocomposite electrode showed superior high rate capability
                      (1043.8 mA h g−1 at 5C) and long-term cycling stability
                      (773.6 mA h g−1 after 500 cycles at 0.5C) in comparison to
                      the pure MnCo2O4 electrode (771.5 mA h g−1 at 5C and 638.9
                      mA h g−1 at 0.5C after 500 cycles). It was believed that
                      the extra phase of Co3O4 may also participate in the
                      electrochemical reactions due to its high electrochemically
                      active nature. Benefiting from the appealing architectural
                      features and striking synergistic effect, the integrated
                      MnCo2O4/Co3O4 nanocomposite anode exhibits excellent
                      electrochemical properties and high cycle stability for
                      LIBs.},
      cin          = {IEK-12},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {38206350},
      UT           = {WOS:001141097500001},
      doi          = {10.1039/D3CP04965E},
      url          = {https://juser.fz-juelich.de/record/1025004},
}