001025007 001__ 1025007
001025007 005__ 20250203103213.0
001025007 0247_ $$2doi$$a10.1002/aenm.202203426
001025007 0247_ $$2ISSN$$a1614-6832
001025007 0247_ $$2ISSN$$a1614-6840
001025007 0247_ $$2datacite_doi$$a10.34734/FZJ-2024-02601
001025007 0247_ $$2WOS$$aWOS:000950238400001
001025007 037__ $$aFZJ-2024-02601
001025007 082__ $$a050
001025007 1001_ $$00000-0002-2073-578X$$aBradbury, Robert$$b0
001025007 245__ $$aVisualizing Reaction Fronts and Transport Limitations in Solid‐State Li–S Batteries via Operando Neutron Imaging
001025007 260__ $$aWeinheim$$bWiley-VCH$$c2023
001025007 3367_ $$2DRIVER$$aarticle
001025007 3367_ $$2DataCite$$aOutput Types/Journal article
001025007 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1712750997_24402
001025007 3367_ $$2BibTeX$$aARTICLE
001025007 3367_ $$2ORCID$$aJOURNAL_ARTICLE
001025007 3367_ $$00$$2EndNote$$aJournal Article
001025007 520__ $$aThe exploitation of high-capacity conversion-type materials such as sulfur in solid-state secondary batteries is a dream combination for achieving improved battery safety and high energy density in the push toward a sustainable future. However, the exact reason behind the low rate-capability, bottlenecking further development of solid-state lithium–sulfur batteries, has not yet been determined. Here, using neutron imaging, the spatial distribution of lithium during cell operation is directly visualized and it is shown that sluggish macroscopic ion transport within the composite cathode is rate-limiting. Observing a reaction front propagating from the separator side toward the current collector confirms the detrimental influence of a low effective ionic conductivity. Furthermore, irreversibly concentrated lithium in the vicinity of the current collector, revealed via state-of-charge-dependent tomography, highlights a hitherto-overlooked loss mechanism triggered by sluggish effective ionic transport within a composite cathode. This discovery can be a cornerstone for future research on solid-state batteries, irrespective of the type of active material.
001025007 536__ $$0G:(DE-HGF)POF4-1221$$a1221 - Fundamentals and Materials (POF4-122)$$cPOF4-122$$fPOF IV$$x0
001025007 536__ $$0G:(BMBF)03XP0115B$$aLISZUBA - Lithium-Schwefel-Feststoffbatterien als Zukunftsbatterie (03XP0115B)$$c03XP0115B$$x1
001025007 588__ $$aDataset connected to DataCite
001025007 7001_ $$0P:(DE-HGF)0$$aDewald, Georg F.$$b1
001025007 7001_ $$0P:(DE-Juel1)192207$$aKraft, Marvin A.$$b2$$ufzj
001025007 7001_ $$00000-0002-0715-2213$$aArlt, Tobias$$b3
001025007 7001_ $$00000-0002-0980-1440$$aKardjilov, Nikolay$$b4
001025007 7001_ $$00000-0002-9221-4756$$aJanek, Jürgen$$b5
001025007 7001_ $$00000-0001-9795-5345$$aManke, Ingo$$b6
001025007 7001_ $$0P:(DE-Juel1)184735$$aZeier, Wolfgang G.$$b7
001025007 7001_ $$00000-0001-8192-996X$$aOhno, Saneyuki$$b8$$eCorresponding author
001025007 773__ $$0PERI:(DE-600)2594556-7$$a10.1002/aenm.202203426$$gVol. 13, no. 17, p. 2203426$$n17$$p2203426$$tAdvanced energy materials$$v13$$x1614-6832$$y2023
001025007 8564_ $$uhttps://juser.fz-juelich.de/record/1025007/files/Advanced%20Energy%20Materials%20-%202023%20-%20Bradbury%20-%20Visualizing%20Reaction%20Fronts%20and%20Transport%20Limitations%20in%20Solid%E2%80%90State%20Li%20S.pdf$$yOpenAccess
001025007 8564_ $$uhttps://juser.fz-juelich.de/record/1025007/files/Advanced%20Energy%20Materials%20-%202023%20-%20Bradbury%20-%20Visualizing%20Reaction%20Fronts%20and%20Transport%20Limitations%20in%20Solid%E2%80%90State%20Li%20S.gif?subformat=icon$$xicon$$yOpenAccess
001025007 8564_ $$uhttps://juser.fz-juelich.de/record/1025007/files/Advanced%20Energy%20Materials%20-%202023%20-%20Bradbury%20-%20Visualizing%20Reaction%20Fronts%20and%20Transport%20Limitations%20in%20Solid%E2%80%90State%20Li%20S.jpg?subformat=icon-1440$$xicon-1440$$yOpenAccess
001025007 8564_ $$uhttps://juser.fz-juelich.de/record/1025007/files/Advanced%20Energy%20Materials%20-%202023%20-%20Bradbury%20-%20Visualizing%20Reaction%20Fronts%20and%20Transport%20Limitations%20in%20Solid%E2%80%90State%20Li%20S.jpg?subformat=icon-180$$xicon-180$$yOpenAccess
001025007 8564_ $$uhttps://juser.fz-juelich.de/record/1025007/files/Advanced%20Energy%20Materials%20-%202023%20-%20Bradbury%20-%20Visualizing%20Reaction%20Fronts%20and%20Transport%20Limitations%20in%20Solid%E2%80%90State%20Li%20S.jpg?subformat=icon-640$$xicon-640$$yOpenAccess
001025007 909CO $$ooai:juser.fz-juelich.de:1025007$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
001025007 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)192207$$aForschungszentrum Jülich$$b2$$kFZJ
001025007 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)184735$$aForschungszentrum Jülich$$b7$$kFZJ
001025007 9131_ $$0G:(DE-HGF)POF4-122$$1G:(DE-HGF)POF4-120$$2G:(DE-HGF)POF4-100$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF4-1221$$aDE-HGF$$bForschungsbereich Energie$$lMaterialien und Technologien für die Energiewende (MTET)$$vElektrochemische Energiespeicherung$$x0
001025007 9141_ $$y2024
001025007 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2023-10-26
001025007 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2023-10-26
001025007 915__ $$0StatID:(DE-HGF)1160$$2StatID$$aDBCoverage$$bCurrent Contents - Engineering, Computing and Technology$$d2023-10-26
001025007 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
001025007 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search$$d2023-10-26
001025007 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2023-10-26
001025007 915__ $$0StatID:(DE-HGF)3001$$2StatID$$aDEAL Wiley$$d2023-10-26$$wger
001025007 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2023-10-26
001025007 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2023-10-26
001025007 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
001025007 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC$$d2023-10-26
001025007 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bADV ENERGY MATER : 2022$$d2023-10-26
001025007 915__ $$0StatID:(DE-HGF)9925$$2StatID$$aIF >= 25$$bADV ENERGY MATER : 2022$$d2023-10-26
001025007 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2023-10-26
001025007 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2023-10-26
001025007 9201_ $$0I:(DE-Juel1)IEK-12-20141217$$kIEK-12$$lHelmholtz-Institut Münster Ionenleiter für Energiespeicher$$x0
001025007 9801_ $$aFullTexts
001025007 980__ $$ajournal
001025007 980__ $$aVDB
001025007 980__ $$aUNRESTRICTED
001025007 980__ $$aI:(DE-Juel1)IEK-12-20141217
001025007 981__ $$aI:(DE-Juel1)IMD-4-20141217